Fluorene To Fluorenone

Briefly explain, with respect to atoms that are present and absent in fluorene, and their relative electronegativities, why fluorene is non-polar. Than 2 ml of 3 M H 2SO 4 were added and the Solid product that accrued was heated with 2 pipettes of Methanol until it was completely. Air Oxidation of Fluorene to Fluorenone —Separation of Products by Column Chromatography CHEM 213 Experiment 6 • Synthesize the fluorene/fluoreneone mixture • Separate the fluorene from fluorenone using the technique of column chromatography • Identify products of the reaction by TLC analysis and infrared (IR) spectrometry 1. The hydrogenation of. It is used to make antimalaria drugs. Now consider the bonding in methanol and water and compare this to fluorene. it has a violet fluorescence, hence its name. It is insoluble in water; soluble in ether and acetone; melting point 116-117 C. Articles of 9H FLUORENE are included as well. Afluorene-utilizing microorganism, identified as a species ofPseudomonas,was isolated from soil severely contaminated from creosote use and was shown to accumulate six major metabolites from fluorene in washed-cell incubations. Subsequent oxidation by the dehydrogenase FlnB results in 9-fluorenone, which is attacked again by DbfA to form 1,1a-dihydroxy-1-hydrofluorene-9-one in an angular dioxygenation (Habe et al. Some of the general examples are: • Synthesis of host for the blue and green phosphorescent organic light emitting diodes (PHOLEDs). 2 Relevant identified uses of the substance or mixture and uses advised against. Type part of your institution name for a list of matches. It can be synthesised from fluorene with the addition of glacial acetic acid and sodium hypochlorite solution, undergoing an oxidation reaction. ) Enter the desired X axis range (e. Sections I (Health Hazard Assessments for Noncarcinogenic Effects) and. Find all the synonyms and alternative words for fluorene at Synonyms. For the further investigation of the DD/DF formation mechanism from PAHs and seeking after the heterogeneous mechanism of PCDD/Fs in incineration processes, we carried out a density functional theory study on the mechanistic aspects of DF formation from phenanthrene (Phe), fluorene (Flu), 9-menthylfluorene (9MF), as well as 9-fluorenone (9FO). Justia Patents Discontinuous Or Differential Coating, Impregnation Or Bond (e. It is insoluble in water; soluble in ether and acetone; melting point 116-117 C. If you want to get pure fluorene, you need to find an addition compound that will precipitate the fluorenone as a derivative, then work on the resulting solution. The mechanism, illustrated below, follows a general oxidation mechanism, beginning with a hydroxide ion deprotonating a fluorene proton under the influence of the catalyst. Fluorene is a member of polycyclic aromatic hydrocarbon (PAH). Some conversion. Reaction constants as well as activation parameters were evaluated. What is the melting point? What does the melting point data tell you? Were there any errors? If so, what caused them? Melting Pont Fluorenone. The fluorenone and fluorenol samples serve as reference spots to determine when the reaction goes to completion. 8 is fluorene, 0. ; Pass a solution of 25 mg fluorenone in ethanol over the resin. Two benzene rings are fused to cyclopentane ring. Fluorenone can be prepared from fluorene by contacting a solution of the latter in dimethyl sulfoxide with molecular oxygen in the presence of a small amount of an alkali-metal hydroxide. 02 cm different, it is not enough to say that they are two distinct substances; rather there is some mixture of trans-stilbene in the dibromide, because some of the characteristics may be similar. a) Although fluorenone is more polar than fluorenol, more specific interactions between fluorenol and silica account for its slow migration in thin-layer chromatography. A mixture of fluorene, fluorenone and fluorenol is examined by TLC and gives the following Rf values: 0. ESPERIENZA 3 – Separazione TLC di fluorene e fluorenone La cromatografia si definisce come la separazione di una miscela di due o più composti diversi (in certi casi ioni) per distribuzione tra due fasi, una delle quali è stazionaria mentre l’altra è in movimento. Circular dichroism spectroscopy revealed that the major enantiomer of anthracene trans-1,2-dihydrodiol was predominantly in the S,S configuration and the major enantiomer of the pyrene trans-4,5-dihydrodiol was predominantly R,R. More over when compared with fluorene, the significantly lower potentials of AFO the respective electron-donating. Type part of your institution name for a list of matches. Further, it is used in functional polymer and in dyes. Origin From its violet. To our knowledge this is the first study on the cometabolic degradation of the three-ring PAHs phenanthrene, anthracene and the four-ring PAH fluoranthene by a fluorene-utilizing species. Moreover, the presence of fluorenone lowers the efficiency quantum yields that inversely follow the fluorenone/fluorene ratio. 9-Fluorenone is used in the preparation of antimalarial drugs. In that time the solution turned colorless. Information for 9-Fluorenone 486-25-9 including 9-Fluorenone CAS NO 486-25-9, 9-Fluorenone Suppliers, 9-Fluorenone Manufacturers, related products of 9-Fluorenone. 02 cm different, it is not enough to say that they are two distinct substances; rather there is some mixture of trans-stilbene in the dibromide, because some of the characteristics may be similar. strain DBF63. Aldrich - F1506 Sigma-Aldrich Corporation www. The latter is obtained by heating fluorenol in methanol with conc. Procedure: Evaporate an aqueous slurry of 1 g of potassium permanganate and 10 g of silica gel in a rotary evaporator at 80-90 degrees until it becomes a free-flowing solid. Use Google or Wikipedia to find the structures of fluorene and 9-fluorenone. Compare Products: Select up to 4 products. 9-Fluorenylmethyl chloroformate (Fmoc chloride) is used to introduce the 9-fluorenylmethyl carbamate (Fmoc) protecting group on amines in peptide synthesis. strain DBF63. In this experiment, separation of fluorene and 9-fluorenone took place using column chromatography. The fluorenone is more polar because it belongs to the ketone family. The hydroxide ions from the sodium hydroxide in the presence of Stark’s catalyst would be able to de-protonate the acidic fluorene protons. An improved process for the production of pure fluorenone by oxidation of fluorene with air or oxygen at ambient temperature in the presence of a quaternary salt, the improvement comprising carrying out the reaction in a suspension of fluorene or a fluorene-containing fraction in an aprotic immiscible with water solvent, such as a α-methyl naphthalene, which contains and is primed with a 30%. Use alumina as the adsorbent. It can be synthesised from fluorenol with the addition of glacial acetic acid and sodium hypochlorite solution, undergoing an oxidation reaction. Fluorene | C13H10 | CID 6853 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards. It can be synthesised from fluorene with the addition of glacial acetic acid and sodium hypochlorite solution, undergoing an oxidation reaction. This was necessary to investigate the feasibility of a 2-step hydrogenation sequence that will convert fluorenone to fluorene and subsequently selectively convert fluorene to cis,cis-perhydrofluorene. Dibenzofuran will be formed if ∙OH adds to C8a, and the order of reactivity follows as 9-fluorenone > 9-methylfluorene > fluorene > phenanthrene. 9-fluorenone has one polar $\ce{C=O}$ bond, but it also has two aromatic rings. Fluorene none listed none listed none listed OSHA Vacated PELs: Fluorene: No OSHA Vacated PELs are listed for this chemical. It is used to make antimalaria drugs. Reserve your 9-fluorenone for lab 3. 9-Fluorenone mp 82-85oC OCH 2CH 3 O H 2N Ethyl 4-Aminobenzoate mp 91-92oC OH O Benzoic Acid mp 122oC PROCEDURE ACID/BASE SEPARATION OF A MIXTURE Review Chapter 15 in Zubrick You will separate a mixture of 9-fluorenone, benzoic acid, and ethyl 4-aminobenzoate by successive acid/base reactions and extractions from ether. Two benzene rings are fused to cyclopentane ring. This is confirmed by the fact that 9-fluorenone is insoluble in water. Continue the TLC analysis of the reaction mixture at 10 minutes intervals until no starting material remains in the reaction mixture. What does fluorenone mean? Information and translations of fluorenone in the most comprehensive dictionary definitions resource on the web. Melting Point Fluorene. Circular dichroism spectroscopy revealed that the major enantiomer of anthracene trans-1,2-dihydrodiol was predominantly in the S,S configuration and the major enantiomer of the pyrene trans-4,5-dihydrodiol was predominantly R,R. Fluorene is a member of polycyclic aromatic hydrocarbon (PAH). Introduction voltammetry on fluorene/fluorenone co-polymers compris- ing 1% fluorenone to investigate the optical and electrical The polyfluorenes (PFs) have emerged as an important effects of fluorenone defects in PFs. ChEBI CHEBI:17922 The simplest member of the class fluoren-9-ones that is 9H-fluorene bearing an oxo substituent at position 9. product, 9-fluorenone, indicates the progress of the reaction. 133 or European Standard EN166. FLUORENE (a-diphenylene methane), C 13 H 10 or (C6H4)2CH2, a hydrocarbon found in coal-tar. com supplies reagents, research chemicals, laboratory glassware, equipment and supplies to the scientific and academic communities. Light emitting devices of polyfluorenes, prepared by Yamamoto and Suzuki polymerisation of the defect. Allow these few drops to enter the sand and silica. [Fluorene Pathway Map] [BBD Main Menu] Page Author(s): Anna Maria Solanas, Jingfeng Feng, Carla Essenberg and Lynda Ellis June 23, 1998 11:35:55 AM CDT Contact Us. Fluorene is a member of polycyclic aromatic hydrocarbon (PAH). The Fluorene is more soluble in that solvent than the fluorenone, but would be likely to oxidise to fluorenone when you try to dry it off. What does fluorenone mean? Information and translations of fluorenone in the most comprehensive dictionary definitions resource on the web. The reaction channel from fluorene and O2 to 9-fluorenone and H2O seems very important, not only because it contains only three elementary reactions, but because the standard reaction Gibbs energies are lower than −80. Fluorene is a precursor to other fluorene compounds; the parent species has few applications. aminofluorenone derivatives are much lower than that of fluorene (Eox=1. I would argue differently from Mike. *Please select more than one item to compare. unreacted fluorene. fluorenone (countable and uncountable, plural fluorenones) (organic chemistry) An aromatic compound with the chemical formula C 13 H 8 O, produced from fluorene via oxidation and used in the manufacture of antimalaria drugs. This experiment involved the oxidation of fluorene to fluorenone under basic conditions with the addition of Stark's catalyst for the reasons listed above. Department of Chemistry, Memorial University, St. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910. More over when compared with fluorene, the significantly lower potentials of AFO the respective electron-donating. Abstract We have synthesized and characterized a new fluorene copolymer exhibiting bright yellow luminescence. Fluorene, Reagent, also known as 9H-fluorene, is a polycyclic aromatic hydrocarbon used as a precursor to several other fluorene compounds. In the end when the reaction is complete, there is only a dark spot at the fluorenol. ) in THF or benzene at 20- 60 °C. ALS Environmental does not sell chemicals, but offers analytical lab testing to determine the presence of various elements and chemical. Fluorene is an apolar molecule, while fluorenone (which i believe is the second molecule you are referring to) is polar, due to the carbonyl group. What is the purpose of this addition? Why is it important to dissolve all of the solids completely?. It can be synthesised from fluorenol with the addition of glacial acetic acid and sodium hypochlorite solution, undergoing an oxidation reaction. *Please select more than one item to compare. The resulting dianion cyclizes to give the fluorenone skeleton. In this lesson we will be taking an in-depth look at an organic compound known as fluorenone. it is finally recrystallised from rather dilute alcohol. A rotary evaporator could help. It's also far-and-away the stable isomer of fluorene, as opposed to (for example) 1H-fluorene: This notation is also used e. com: all content. Fluorene Revision Date 18-Jan-2018 Component CAS-No Weight % Fluorene 86-73-7 >95 4. It is not synthesized commercially but is obtained from middle oil fraction of coal tar. What does fluorenone mean? Information and translations of fluorenone in the most comprehensive dictionary definitions resource on the web. 9-Fluorenone exists in both the vapor and particulate phases in the ambient atmosphere and will be degraded by reaction with photochemically produced hydroxyl radicals. The comparison of the cyclic voltammograms of fluorene, 2,7-diaminofluorene, fluorenone and aminofluorene (46,48)leads us to. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910. CHEMWILL Asia is a leading manufacturer of 2-Bromo-9-fluorenone,CAS 3096-56-8. it is finally recrystallised from rather dilute alcohol. com: all content. Fluorene-9-carboxylic acid is a precursor to pharmaceuticals. aminofluorenone derivatives are much lower than that of fluorene (Eox=1. An improved process for the production of pure fluorenone by oxidation of fluorene with air or oxygen at ambient temperature in the presence of a quaternary salt, the improvement comprising carrying out the reaction in a suspension of fluorene or a fluorene-containing fraction in an aprotic immiscible with water solvent, such as a α-methyl naphthalene, which contains and is primed with a 30%. Abstract: We discover the eutectic state in binary mixtures of fluorene-fluorenone. Fluorene derivatives are drawing a lot of interest in the fields of photoreceptors, optical functional materials, functional resins, organic intermediates, and OLEDs. Start studying ORGO Experiment #5 Separation of Fluorene and Fluorenone by Column Chromatography. To the solution was slowly added a solution of thione 42 (2. Cells grown on fluorene exhibit pronounced 9-fluorenol dehydrogenase activity. As a result, a pathway for fluorene transformation by USTB-C was. Which compound do you think will travel down the column first? Procedure: Packing the column. 9-Fluorenone has been extensively used as a precursor to synthesize a variety of organic electronic materials. It emits violet fluorescent color. Place this into a 125 mL Erlenmeyer flask and add about 10 mL of dichloromethane, CH2Cl2 (an older name, still in use, is methylene chloride). Definition of fluorenone in the Definitions. Compounds: 9-fluorenone, 9-fluorenol. Instead, fluorene-tethered iso-xazole 6 was isolated in 60% yield. - Find MSDS or SDS, a COA, data sheets and more information. John's, NL A1B 3X7, Canada. More over when compared with fluorene, the significantly lower potentials of AFO the respective electron-donating. At the end of the workshift, wash any areas of the body that may have contacted Fluorene, whether or not known skin contact has occurred. 2-Bromo-9-Fluorenone,3096-56-8,C13H7BrO. Bisphenol, bisalcohol and bisamine monomer, possessing the fluorene skelton of the configuration called a cardo(hinge) structure, applicable as a raw material and reforming agent for various types of optical resin. La fluorénone est un composé organique aromatique de formule brute C 13 H 8 O. Efficient separation of compounds in GC is depend. CHEM 2229 EXP 2: Oxidation of 9-Fluorenol to 9-Fluorenone with Polymer-supported Cr (VI) Background: Chrome-6, Cr(VI), in the form of chromium trioxide, sodium dichromate or potassium dichromate, is frequently used for the oxidation of secondary alcohols to the corresponding ketones. A 100mg of the mixtures Fluorene (1) and Fluorenone (2) was added to the column. [1] 8 relations: Acetic acid , Antimalarial medication , Aromaticity , Fluorene , Fluorenol , Organic compound , Sodium hypochlorite , 1,8-Diazafluoren-9-one. The synthetic sequence involving the oxidation of fluorene to fluorenone and the reduction of fluorenone to fluorenol can be extended by preparing the title compounds via the intermediate 9-chlorofluorene. Use the TLC technique as described in Techniques 17 to monitor the progress of this oxidation reaction. * Do not eat, smoke, or drink where Fluorene is handled, processed, or stored, since the chemical can be swallowed. 1 Revision Date 01/06/2009. Fluorene, Acenaphthene, Quinoline, Methylnaphthalene, Dibenzofuran, Indene, Indole, 9-Fluorenone, Carbazole, Anthracene Company Introduction Sinochem Hebei Xinbao Chemical Technology Co. Origin From its violet. 9-Fluorenone exists in both the vapor and particulate phases in the ambient atmosphere and will be degraded by reaction with photochemically produced hydroxyl radicals. Melting Point Fluorene. Break off the tip of the `column' (hold the pipette near the bend when breaking) and when the Ligroin just disappears through the sand add the solution of fluorene/fluorenone to the top of the column dropwise until the sample has been loaded on the column. Elle est utilisée pour faire des médicaments antipaludéen. It is used to make antimalaria drugs. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then adding all of these products together. Reaction engineering simulations of a fluidized-bed reactor for selective oxidation of fluorene to 9-fluorenone. There is no warranty of accuracy or completeness of any information contained herein. Fluorenone is an aromatic organic compound with the chemical formula C13H8O. The efficacy of complete degradation of the titled polynuclear aromatics (PNA) was evaluated and the products were examined. fluorene and fluorenone will be separated by column chromatography. 02 cm different, it is not enough to say that they are two distinct substances; rather there is some mixture of trans-stilbene in the dibromide, because some of the characteristics may be similar. , 100, 200) 2. Add a few more drops and repeat the process until all the fluorene/9-fluorenone mix has visibly been washed out of the sand and into the silica gel (the sand is no longer yellow). A fluorene-degrading strain of Sphingobacterium was isolated from polycyclic aromatic hydrocarbon-contaminated soil near a mine-impacted area in Korea. For the further investigation of the DD/DF formation mechanism from PAHs and seeking after the heterogeneous mechanism of PCDD/Fs in incineration processes, we carried out a density functional theory study on the mechanistic aspects of DF formation from phenanthrene (Phe), fluorene (Flu), 9-menthylfluorene (9MF), as well as 9-fluorenone (9FO). Sections I (Health Hazard Assessments for Noncarcinogenic Effects) and. Information for 9-Fluorenone 486-25-9 including 9-Fluorenone CAS NO 486-25-9, 9-Fluorenone Suppliers, 9-Fluorenone Manufacturers, related products of 9-Fluorenone. IV 9 19 led to the formatioil of fluorenone, probably by anionic oxidation (16). I would argue differently from Mike. Based on melting point analysis and its bright yellow appearance, I determined it to be 9-fluorenone. (organic chemistry) A polycyclic aromatic hydrocarbon consisting of two benzene rings joined together directly, and also via a methylene bridge; it is used in light-emitting diodes. Preparation chromatographic separations are generally not equilibrium processes. The benzene eluate yielded a yellow compound which melted at 80-81 ~ after crystallization from petroleum ether. Afluorene-utilizing microorganism, identified as a species ofPseudomonas,was isolated from soil severely contaminated from creosote use and was shown to accumulate six major metabolites from fluorene in washed-cell incubations. a) Although fluorenone is more polar than fluorenol, more specific interactions between fluorenol and silica account for its slow migration in thin-layer chromatography. Oxidation of fluorene gives fluorenone, which is nitrated to give commercially useful derivatives. Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data, as outlined in the. After the solution was cooled down to RT, 48 mg NaBH 4 was dissolved and let it react for 20 min. The proposed formation mechanism elucidates a new source of 9-fluorenone in the atmosphere. A 100mg of the mixtures Fluorene (1) and Fluorenone (2) was added to the column. Even in other markets, myTCI account registration allows you to use useful functions such as "My Favorites". 02 cm different, it is not enough to say that they are two distinct substances; rather there is some mixture of trans-stilbene in the dibromide, because some of the characteristics may be similar. Oxidation of fluorene gives fluorenone, which is nitrated to give commercially useful derivatives. Fluorene, Acenaphthene, Quinoline, Methylnaphthalene, Dibenzofuran, Indene, Indole, 9-Fluorenone, Carbazole, Anthracene Company Introduction Sinochem Hebei Xinbao Chemical Technology Co. Further, it is used in functional polymer and in dyes. 5 [pdf] chem vilo cdna synthesis invitrogen 51lb: that the first vapors are [mostly] comming from synthesis of fluorene to fluorenone mechanism the compound with a. Furthermore, fluorene is one of the highest plentiful polycyclic aromatic hydrocarbons (PAHs) in the surroundings due to its high volatility. Process for the production of fluorenone by catalytic oxidation of fluorene Abstract. Reaction engineering simulations of a fluidized-bed reactor for selective oxidation of fluorene to 9-fluorenone. By incorporating fluorene into the structure of resins, we can produce resins with unique characteristics, e. Carefully review the (M)SDS below to see if it's the version you're looking for. More over when compared with fluorene, the significantly lower potentials of AFO the respective electron-donating. In order to ensure a complete π-stacking of the active layer, a 9-fluorenone monomeric unit (FO. 67cm for 9-fluorenone. [About Reference Price] About Reference Price Reference price is published by MOLBASE platform, Which was calculated with quotation and purchasing data by scientific algorithm. It is a fluorene derivative. Metabolism of fluorene was shown to proceed via the 9-fluorenone pathway to form o-phthalic acid and protocatechuic acid. Green Guardee is one of the most professional fluorene manufacturers and suppliers in China, engaged in producing fluorene OLED material. In that time the solution turned colorless. The 9-Fluorenone-2-carboxylic acid molecule consists of 8 Hydrogen atom(s), 14 Carbon atom(s) and 3 Oxygen atom(s) - a total of 25 atom(s). Chlorination of fluorene in polluted humus poor lake water gave a chlorinated derivative tentatively identified as 2-chlorofluorene (Johnsen et al. Reserve your 9-fluorenone for lab 3. Show transcribed image text 2. [Fluorene Pathway Map] [BBD Main Menu] Page Author(s): Anna Maria Solanas, Jingfeng Feng, Carla Essenberg and Lynda Ellis June 23, 1998 11:35:55 AM CDT Contact Us. There is no warranty of accuracy or completeness of any information contained herein. Subsequent oxidation by the dehydrogenase FlnB results in 9-fluorenone, which is attacked again by DbfA to form 1,1a-dihydroxy-1-hydrofluorene-9-one in an angular dioxygenation (Habe et al. *Please select more than one item to compare. 9-Fluorenone exists in both the vapor and particulate phases in the ambient atmosphere and will be degraded by reaction with photochemically produced hydroxyl radicals. of methyl fluorene as a hesitant compound in the exhaust [17]. Fluorene is an apolar molecule, while fluorenone (which i believe is the second molecule you are referring to) is polar, due to the carbonyl group. Fluorene and toluene have the same types of bonding: aromatic π systems and non-aromatic C–C and C–H bonds, so fluorene molecules experience roughly equal attraction to toluene molecules as they do to other fluorene molecules and fluorene is highly soluble in toluene. Fluorene none listed none listed none listed OSHA Vacated PELs: Fluorene: No OSHA Vacated PELs are listed for this chemical. 1H Nuclear Magnetic Resonance (NMR) Spectrum of Fluorene with properties. Meaning of fluorene. CAS号查询致力于为化学行业用户免费提供fluorenone的CAS号、中文名称、英文名称相互转换服务,同时也包括fluorenone的性质、化学式、分子结构、密度、熔点、沸点等信息。. opacus 4a and 557, and R. 02 cm different, it is not enough to say that they are two distinct substances; rather there is some mixture of trans-stilbene in the dibromide, because some of the characteristics may be similar. com supplies reagents, research chemicals, laboratory glassware, equipment and supplies to the scientific and academic communities. The data presented not only elaborate on the HOMO-LUMO tuning of 9‐fluorenone systems but also enable the consideration of 9‐fluorenones as analogous models for HOMO-LUMO tuning in other more complex polyaromatic systems such as bifluorenylidenes. Oxidation of fluorene gives fluorenone, which is nitrated to give commercially useful derivatives. Cells grown on fluorene exhibit pronounced 9-fluorenol dehydrogenase activity. Even in other markets, myTCI account registration allows you to use useful functions such as "My Favorites". 3 is fluorenol. In the experiment, the reducing agent is allowed to react with 9-fluorenone, and after the reaction is complete, sulfuric acid is added. Definition of fluorenone in the Definitions. Note: Product prices and availability are subject to change without notice. 5% by GC which is a basic material used in many fields. 2 Relevant identified uses of the substance or mixture and uses advised against. Our primary points of discussion will be on its structure, solubility, and polarity. The emission properties of. The solution was then eluted with pet ether and 50mL flasks were used as receivers. Add a magnetic stir bar and heat on a stirrer-hot plate, set as low as possible, under your fume hood. explainshow the mechanism to convert 9-fluorenol to 9-methoxy fluorene using a nucleophilic substitution reaction with, Hire Chemistry Expert, Ask Academics Expert, Assignment Help, Homework Help, Textbooks Solutions. Intact fungal cultures metabolized fluorene to 9-hydroxyfluorene via 9-fluorenone. fluorene +‎ -one. The mechanism, illustrated below, follows a general oxidation mechanism, beginning with a hydroxide ion deprotonating a fluorene proton under the influence of the catalyst. In addition, fluorene based systems possess sole photo physical properties such as high fluorescent quantum yield, huge photo stability, and excellent hole-transporting properties [22,23]. 61 g 9-fluorenone was dissolved in 6 mL methanol under warming. net dictionary. Advances in Physical Chemistry is a peer-reviewed, Open Access journal that publishes original research articles as well as review articles on experimental and theoretical investigations into physical chemistry and chemical physics. 9-Fluorenone is an ambrosial amoebic admixture with the actinic blueprint C13H8O. It is insoluble in water; soluble in ether and acetone; melting point 116-117 C. Reaction engineering simulations of a fluidized-bed reactor for selective oxidation of fluorene to 9-fluorenone. Afluorene-utilizing microorganism, identified as a species ofPseudomonas,was isolated from soil severely contaminated from creosote use and was shown to accumulate six major metabolites from fluorene in washed-cell incubations. Fluorenone is an aromatic organic compound with the chemical formula C13H8O. CHEMWILL Asia is a leading manufacturer of 2-Bromo-9-fluorenone,CAS 3096-56-8. it has a violet fluorescence, hence its name. It's also far-and-away the stable isomer of fluorene, as opposed to (for example) 1H-fluorene: This notation is also used e. Chlorination of fluorene in polluted humus poor lake water gave a chlorinated derivative tentatively identified as 2-chlorofluorene (Johnsen et al. The addition of 9-fluorenone to cultures growing on fluorene showed that 9-fluorenone inhibits fluorene degradation. Fluorenone is yellow, which gives a yellow solution when dissolved in a solvent. Maximum 9-fluorenone selectivity in air oxidation of fluorene as function of catalyst composition (Vo: Fe : Cs atomic ratio) and its calcination temperature at various reaction temperature (CF = 0. Fluorene was visible only under UV light because it is a colorless compound, unlike 9-fluorenone which is yellow. It was confirmed to be fluorenone by determining the mixed melting point with an authentic sample of fluorenone and by spectroscopic analysis. Due to the presence of an oxygen molecule, the chemical compound fluorenone is more polar than fluorene. : Regio - and stereospecific oxidation of fluorene, dibenzofuran, and dibenzothiophene by naphthalene dioxygenase from Pseudomonas sp. To the solution was slowly added a solution of thione 42 (2. Non è sintetizzato commercialmente, ma è ottenuto dalla frazione intermedia nel processo di produzione del catrame, in particolare dall'ossidazione del fluorene con ossigeno. The 9-Fluorenone-2-carboxylic acid molecule consists of 8 Hydrogen atom(s), 14 Carbon atom(s) and 3 Oxygen atom(s) - a total of 25 atom(s). The Reagent grade denotes that this chemical is the highest quality commercially available and th. After the solution was cooled down to RT, 48 mg NaBH 4 was dissolved and let it react for 20 min. opacus 4a and 557, and R. After cooling to room temperature, the reaction mixture is over saturated, and agitating it with. fluorenone (countable and uncountable, plural fluorenones) (organic chemistry) An aromatic compound with the chemical formula C 13 H 8 O, produced from fluorene via oxidation and used in the manufacture of antimalaria drugs. This dissertation describes the thermodynamic and optical study of 16 fluorene derivatives, 4 fluorenone derivatives and 3 naphthalene derivatives, some of which were synthesized for this purpose. What is fluorene used for? Most of the PAHs are used to conduct research. A 100mg of the mixtures Fluorene (1) and Fluorenone (2) was added to the column. More particularly, the invention relates to a process for obtaining fluorenone in good yields by the oxidation of fluorene, which process comprises contacting a solution of fluorene in dimethyl sulfoxide (DMSO) with molecular oxygen in the presence of an alkali-metal hydroxide, wherein the alkali-metal hydroxide. 9-Fluorenone | C13H8O | CID 10241 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety. Explain your answer in terms of each compounds structure and polarity and its interaction with the alumina stationary phase 2. The Reagent grade denotes that this chemical is the highest quality commercially available and th. Continue the TLC analysis of the reaction mixture at 10 minutes intervals until no starting material remains in the reaction mixture. 100 grams Fluorene to mol = 0. Sections I (Health Hazard Assessments for Noncarcinogenic Effects) and. 9H-Fluorene-9-one. It is a fluorene derivative. hydroxyphenyl)fluorene or 9,9 bis(4-hydroxy-3- phenylphenyl)fluorene by the condensation of 9- fluorenone with phenol or o phenylphenol in the presence of methanesulfonic acid. 9-Fluorenylmethyl chloroformate (Fmoc chloride) is used to introduce the 9-fluorenylmethyl carbamate (Fmoc) protecting group on amines in peptide synthesis. Maximum 9-fluorenone selectivity in air oxidation of fluorene as function of catalyst composition (Vo: Fe : Cs atomic ratio) and its calcination temperature at various reaction temperature (CF = 0. Since conjugated polymer films are very efficient at funneling excitons from high-energy sites (e. This experiment involved the oxidation of fluorene to fluorenone under basic conditions with the addition of Stark's catalyst for the reasons listed above. Furthermore, fluorene is one of the highest plentiful polycyclic aromatic hydrocarbons (PAHs) in the surroundings due to its high volatility. On the nature of the fluorenone-based emission in oxidized poly (dialkyl-fluorene) s. Manufacturer: China: As an ISO 9001 qualified company, we are mainly specialized in producing high quality but low price Pharmaceutical intermediates, APIs, synthetic intermediates, as well as some materials in dyes industries, almost half of the goods are for exporting. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then adding all of these products together. : 486-25-9 1. The focus of this lesson will be on a specific organic reaction in which fluorene is oxidized to fluorenone. , Ltd is professional to manufacture 9-Fluorenone and other Fluorene derivatives which are used as organic intermediate, Oled intermediate and electronic materials. This dissertation describes the thermodynamic and optical study of 16 fluorene derivatives, 4 fluorenone derivatives and 3 naphthalene derivatives, some of which were synthesized for this purpose. fluorene degradation sequence is proposed to be initiated by oxidation ofthe fluorene methylene group to 9-fluorenol. SAFETY DATA SHEET Version 3. * On skin contact with Fluorene, immediately wash or shower to remove the chemical. Information for 9-Fluorenone 486-25-9 including 9-Fluorenone CAS NO 486-25-9, 9-Fluorenone Suppliers, 9-Fluorenone Manufacturers, related products of 9-Fluorenone. First-aid measures General Advice If symptoms persist, call a physician. Fluorene Compound Information and Applications for GC (Gas Chromatography) and LC (Liquid Chromatography) Analysis. Additional information on 2-Bromo-9-fluorenone,CAS 3096-56-8. Allow your recrystallized product to dry in your drawer until next lab period. 50 grams Fluorene to mol = 0. N-Vinyl nitrones derived from fluorenone have been prepared via a copper-mediated coupling between fluorenone oxime and vinyl boronic acids. *Please select more than one item to compare. 62 mmol) in P(OEt)3 (30 mL) over a period of 20 min. Since conjugated polymer films are very efficient at funneling excitons from high-energy sites (e. 9-Fluorenylmethyl chloroformate (Fmoc chloride) is used to introduce the 9-fluorenylmethyl carbamate (Fmoc) protecting group on amines in peptide synthesis. Measure an IR spectrum of your product as a thin film (read experiment 3 of Chem 273a and/or ask your TA to tell you how to do this) and compare it to. Fluorene-9-carboxylic acid is a precursor to pharmaceuticals. it has a violet fluorescence, hence its name. 9-Fluorenone has been extensively used as a precursor to synthesize a variety of organic electronic materials. Use the TLC technique as described in Techniques 17 to monitor the progress of this oxidation reaction. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910. If your institution is not listed, please contact your librarian. ) in THF or benzene at 20- 60 °C. Procedure: Evaporate an aqueous slurry of 1 g of potassium permanganate and 10 g of silica gel in a rotary evaporator at 80-90 degrees until it becomes a free-flowing solid. Column Chromatography of the Fluorene-Fluorenone Mixture Prepare a microscale chromatographic column exactly as described at the beginning of this chapter (see Fig. ) Check here for automatic Y scaling 3. High refractive index, High heat resistance, Low birefringence. Compounds: 9-fluorenone, 9-fluorenol. Bisphenol Fluorene Market Overview and Introduction. strain NCIB 9816-4. The Reagent grade denotes that this chemical is the highest quality commercially available and th. What is the purpose of this addition? Why is it important to dissolve all of the solids completely?. 2-Aminofluorene, 3,6-bis-(dimethylamino)fluorene, and 2,7-diiodofluorene are precursors to dyes. It is insoluble in water; soluble in ether and acetone; melting point 116-117 C. explainshow the mechanism to convert 9-fluorenol to 9-methoxy fluorene using a nucleophilic substitution reaction with, Hire Chemistry Expert, Ask Academics Expert, Assignment Help, Homework Help, Textbooks Solutions. Which compound do you think will travel down the column first? Procedure: Packing the column. Chemsrc provides 9H FLUORENE(CAS#:86-73-7) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. An improved process for the production of pure fluorenone by oxidation of fluorene with air or oxygen at ambient temperature in the presence of a quaternary salt, the improvement comprising carrying out the reaction in a suspension of fluorene or a fluorene-containing fraction in an aprotic immiscible with water solvent, such as a α-methyl naphthalene, which contains and is primed with a 30%. Search Results for 'chromatographic separation of fluorene and fluorenone' Fatty Acid Determination Using Gas Chromatography the equilibrium state as possible. Welcome to buy quality products from our factory. Oxidation of Fluorene to Fluorenone C13H10 + O2 = C13H8O + H2O. Fluorene is a precursor to other fluorene compounds; the parent species has few applications. Oxidation of fluorene gives fluorenone, which is nitrated to give commercially useful. SAFETY DATA SHEET Version 3. what is the reaction mechanism for the conversion of 9-fluorenone to 9-fluorenol via sodium borohydride and aqueous acid reduction. Furthermore, fluorene is one of the highest plentiful polycyclic aromatic hydrocarbons (PAHs) in the surroundings due to its high volatility. It is not synthesized commercially but is obtained from middle oil fraction of coal tar.
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Here are Six Political Moments from the 2018 Grammys January 29 2018 by Patrice Lee Onwuka
Debbie Wasserman Schultz, Nancy Pelosi Pooh-pooh $1,000 Bonuses from Tax Reform January 26 2018 by Patrice Lee Onwuka
Walt Disney Heiress Thrashed Tax Reform, but Disney Company Gives Employees Tax Reform Bonuses, Investments January 25 2018 by Patrice Lee Onwuka
Cashier-free Amazon Store Opens in Nation's First $15-Minimum-Wage City January 24 2018 by Patrice Lee Onwuka
Disney Credits Tax Reform for Its $50 Mil Education Investment, $1,000 Bonuses January 24 2018 by Patrice Lee Onwuka
Congress Made New Changes to 529 Plans that Parents Will Celebrate January 23 2018 by Patrice Lee Onwuka
Kristen Bell Opens Girl Power Sag Awards with Cheap Shot at Melania Trump January 22 2018 by Patrice Lee Onwuka
Feminist Slams ‘Fixer Upper’ Stars Chip & Joanna for Having 5th Child January 17 2018 by Patrice Lee Onwuka
Costco Shocks Customers by Exposing the High Price of Seattle’s Soda Tax January 16 2018 by Patrice Lee Onwuka
Condoleeza Rice Warns Against #MeToo Creating Snowflakes and Triggering Backlash January 15 2018 by Patrice Lee Onwuka
Walmart Announces Higher Starting Wages, Bonuses, and Benefits Thanks to Tax Reform January 11 2018 by Patrice Lee Onwuka
Utility Companies Cut Your Utility Bills Thanks to Tax Cuts January 11 2018 by Patrice Lee Onwuka
Say Goodbye to Busboys at Red Robin Thanks to Minimum Wage Hikes January 10 2018 by Patrice Lee Onwuka
USPS is Losing Money, But Blame It on Washington Not Amazon January 5 2018 by Patrice Lee Onwuka
No, Iceland Didn’t Just Make It Illegal to Pay Women Less Than Men January 5 2018 by Patrice Lee Onwuka
California Has Brewed Up a Common-Sense Solution to Drunk Driving January 4 2018 by Patrice Lee Onwuka
Top Hollywood Women Launch Time’s Up as the Answer to #MeToo, but Don’t Be Fooled January 3 2018 by Patrice Lee Onwuka
What You Need to Know About New York's Paid Leave Plan January 3 2018 by Patrice Lee Onwuka
18 States Hike Minimum Wage in 2018, Young Female Workers May Suffer January 2 2018 by Patrice Lee Onwuka
Ivanka Trump Visit Triggers Connecticut Parents to Pull Kids Out of School December 22 2017 by Patrice Lee Onwuka
Capitol Hill Just Passed a #GoodDealforWomen Through Tax Reform December 19 2017 by Patrice Lee Onwuka
California’s $15 Minimum Wage to Cost 400,000 Jobs – Many for Women December 18 2017 by Patrice Lee Onwuka
Pew: Gender Discrimination, Sexual Harassment are Problems but Not Universal December 15 2017 by Patrice Lee Onwuka
Alyssa Milano, John Oliver Aren’t for Saving the Internet but Internet Control December 14 2017 by Patrice Lee Onwuka
Feminism is 2017’s Word of the Year But Women Still Don’t Know What It Means December 13 2017 by Patrice Lee Onwuka
San Francisco Embraces Everyone but Delivery Robots December 12 2017 by Patrice Lee Onwuka
Jobs Report: One Million More Women Are Working Since November 2016 December 8 2017 by Patrice Lee Onwuka
What Paris Hilton Could Teach Chelsea Handler About Grace in Crisis December 8 2017 by Patrice Lee Onwuka
Kellyanne Conway Had a #MeToo Moment Too, But No One Paid Attention Because of Politics December 7 2017 by Patrice Lee Onwuka
Mark Zuckerberg’s Paternity Leave Tells Us 3 Things About Paid Leave, Millennials December 6 2017 by Patrice Lee Onwuka
Sheryl Sandberg Calls Out the Chilling Effect Between Sexes Following Harassment Revelations December 5 2017 by Patrice Lee Onwuka
Three Ways to Maximize Your Last Paychecks of 2017 December 1 2017 by Patrice Lee Onwuka
Meghan Markle Giving Up Her Career for Prince Harry Doesn’t Make Her a Bad Woman November 29 2017 by Patrice Lee Onwuka
Susan Sarandon is Still Anti-Hillary, The Left Blasts Her For It November 28 2017 by Patrice Lee Onwuka
FCC’s Thanksgiving Blessing was to End Internet Neutrality Regulations November 27 2017 by Patrice Lee Onwuka
Black Friday Protests Dwindle Exposing This Uncomfortable Truth November 27 2017 by Patrice Lee Onwuka
Kathy Griffin’s Sadistic Trump Joke Left Her Jobless, She’s Not a Victim November 21 2017 by Patrice Lee Onwuka
New York Wants to Dictate When You Work November 20 2017 by Patrice Lee Onwuka
Bernie Sanders Blatantly Gives Bill Clinton, Al Franken a Pass on Sexual Harassment November 20 2017 by Patrice Lee Onwuka
Do Winter Blizzards Call for Paid Leave Too? November 15 2017 by Patrice Lee Onwuka
‘The Simpsons’ Calling Kellyanne Conway a Nazi is a Sexist, Racist Cheap Shot November 14 2017 by Patrice Lee Onwuka
How Zero Tolerance Polices Backfire in the Age of #MeToo November 13 2017 by Patrice Lee Onwuka
Three G.I. Janes from American History that Make Women Proud on Veterans Day November 10 2017 by Patrice Lee Onwuka
TSA Failing Undercover Weapons Tests – Again, and It’s Disturbing November 10 2017 by Patrice Lee Onwuka
NAACP Exploits NFL Protests to Ban "Star-Spangled Banner" as National Anthem November 9 2017 by Patrice Lee Onwuka
Women in Congress Have an Answer to Paid Leave November 8 2017 by Patrice Lee Onwuka
Sexist LA Times Columnist Attacks Sarah Huckabee Sanders’ Looks November 6 2017 by Patrice Lee Onwuka
Explosive: DNC, Hillary Clinton Campaign Rigged the Party Nomination for Her November 3 2017 by Patrice Lee Onwuka
Eva Longoria is Desperately Wrong to Push the Latina Pay Gap November 2 2017 by Patrice Lee Onwuka
Shame on Cosmo for Normalizing Incest – Again November 2 2017 by Patrice Lee Onwuka
Poll: Most Women Love Tech but Only Half Think It’ll Improve Their Life November 1 2017 by Patrice Lee Onwuka
2018 Obamacare Premiums to Leave Even Wider Hole in Your Wallet October 30 2017 by Patrice Lee Onwuka
Walmart Debuts Robots to Make (Holiday) Shopping Better October 30 2017 by Patrice Lee Onwuka
NAACP Issues Inane Flying-While-Black Advisory, Please Keep It to Yourselves October 27 2017 by Patrice Lee Onwuka
President Trump’s Opioid Attack Plan: Personal, Practical, and Policy October 26 2017 by Patrice Lee Onwuka
UPenn Teacher Helps Black Women by Discriminating Against White Men October 24 2017 by Patrice Lee Onwuka
Campus Sexual Assault: The Distressing Fight Mothers Face for Their Sons, Advice to Young Women October 23 2017 by Patrice Lee Onwuka
IRS to Hold Tax Returns Hostage to Enforce Obamacare October 20 2017 by Patrice Lee Onwuka
ABC’s Misleading Workplace Sexual Harassment Poll Pushes an Agenda October 19 2017 by Patrice Lee Onwuka
‘The Big Bang Theory’ Actress Counsels Actresses to be Modest, Triggers Feminist Backlash October 17 2017 by Patrice Lee Onwuka
No, NFL Protests Aren't About the Gender Pay Gap October 16 2017 by Patrice Lee Onwuka
Ivanka Trump to Boost Global Women Entrepreneurs Via World Bank Fund October 16 2017 by Patrice Lee Onwuka
President Trump’s Anti-Regulation Crusade may be Working in Americans’ Eyes October 13 2017 by Patrice Lee Onwuka
Lawmakers Try to Stop Secretary DeVos on Campus Sexual Assault Policy October 13 2017 by Patrice Lee Onwuka
Black Lives Matter Group Opposes Free Speech for Every American October 12 2017 by Patrice Lee Onwuka
Harvey Weinstein’s Open Secret Exposes Hypocrisy on the Left October 10 2017 by Patrice Lee Onwuka
Marc Jacobs Doubles Down on Free Expression for Designers, Artists October 10 2017 by Patrice Lee Onwuka
On Columbus Day, Give Him a Break October 9 2017 by Patrice Lee Onwuka
Company Behind Fearless Girl Statute Admits Gender Pay Issues October 9 2017 by Patrice Lee Onwuka
Three Bright Spots for Women in Today’s Jobs Report October 6 2017 by Patrice Lee Onwuka
Half of Americans Can’t Afford More than $100 in Healthcare Premiums October 4 2017 by Patrice Lee Onwuka
One Tech Company Changed Approach to Promotions, Women Won Big October 3 2017 by Patrice Lee Onwuka
Librarian Rejects Dr. Seuss Books Because Melania Trump Sent Them September 29 2017 by Patrice Lee Onwuka
Amber Rose’s Slutwalk is a Stunt Not Empowerment September 29 2017 by Patrice Lee Onwuka
Do We Want a Feminist ‘Will & Grace’ Reboot? September 26 2017 by Patrice Lee Onwuka
Hillary Clinton Slams Women Who Support Trump as “Publicly Disrespecting Themselves” September 26 2017 by Patrice Lee Onwuka
Betsy DeVos Ends Obama-Era Policies on School Sexual Assault September 22 2017 by Patrice Lee Onwuka
Washington Wants Black Households to Trade Privacy for Cash September 22 2017 by Patrice Lee Onwuka
Half of College Women Get This Wrong about Hate Speech September 20 2017 by Patrice Lee Onwuka
Joe Biden Slams Socialist Universal Basic Income Idea September 19 2017 by Patrice Lee Onwuka
Millennials Would Trade Right to Vote for Student Loan Freedom September 18 2017 by Patrice Lee Onwuka
Feminists Attack Starbucks's Pumpkin Spice Lattes for Funding White Supremacy September 15 2017 by Patrice Lee Onwuka
DeVos Backlash Incites Dangerous Language September 14 2017 by Patrice Lee Onwuka
Over One in Three Americans Can’t Name Any 1st Amendment Rights September 12 2017 by Patrice Lee Onwuka
Miss America Pageant Gets Political and Blatantly Anti-Trump September 11 2017 by Patrice Lee Onwuka
Melania Trump Staffs Fewer People than Michelle Obama – A Savings for Taxpayers September 8 2017 by Patrice Lee Onwuka
Hillary Clinton Asks 'What Happened?' in 2016 September 7 2017 by Patrice Lee Onwuka
Kim Kardashian Still Eschews One Label: Feminist September 5 2017 by Patrice Lee Onwuka
Jerry Springer Rides the $15 Minimum Wage Wagon September 5 2017 by Patrice Lee Onwuka
A $20 Question: Will Harriet Tubman be on the Bill? September 1 2017 by Patrice Lee Onwuka
Estee Lauder Faces Heat Over Paid Leave for Dads August 31 2017 by Patrice Lee Onwuka
No, Melania’s Shoes are Not the Story, Texas is August 30 2017 by Patrice Lee Onwuka
Illinois Governor Shuts Down $15 Minimum Wage August 28 2017 by Patrice Lee Onwuka
Amy Schumer's Equal Pay Problem August 25 2017 by Patrice Lee Onwuka
Poll: Nearly Three Out of Four Americans Would Die to Defend Freedom of Speech August 25 2017 by Patrice Lee Onwuka
Here’s Another Way Women Suffer from Minimum Wage Increases August 24 2017 by Patrice Lee Onwuka
Oops! Social Security Website Misdirects $11 Mil to Thieves August 23 2017 by Patrice Lee Onwuka
D.C. Raises Minimum Wage, Diners Foot the Bill August 21 2017 by Patrice Lee Onwuka
What Dr. Ben Carson Shows Us about Confronting Hateful Ideas August 17 2017 by Patrice Lee Onwuka
Hope Brings Another Woman to Trump Leadership Circle August 17 2017 by Patrice Lee Onwuka
Helen Mirren’s Feminism is about Anti-Trump and Potty-Mouths August 16 2017 by Patrice Lee Onwuka
CFPB Crackdown May Trap Borrowers in a Different Debt Trap August 14 2017 by Patrice Lee Onwuka
Sheryl Sandberg Leans In to One-Size-Fits-All Paid Leave Plan August 10 2017 by Patrice Lee Onwuka
Café Charges 18% Man Tax to Close the Gender Pay Gap August 9 2017 by Patrice Lee Onwuka
College STEM Women Claim to be Sexism Victims August 7 2017 by Patrice Lee Onwuka
A Sexism Rating Coming to a Movie Near You August 3 2017 by Patrice Lee Onwuka
IRS Rehires Hundreds of Fired Workers Despite Serious Transgressions August 3 2017 by Patrice Lee Onwuka
Study: MD County to Lose 47,000 jobs because of $15 Minimum Wage August 2 2017 by Patrice Lee Onwuka
Adam Carolla Schools Congress on Campus Free Speech July 31 2017 by Patrice Lee Onwuka
How One Tech Company is Taking on the Future of Work July 28 2017 by Patrice Lee Onwuka
Governor Christie Shuts Down Costly Paid Leave Expansion Bill July 27 2017 by Patrice Lee Onwuka
Teachers’ Union Boss Plays the Race Card against Secretary DeVos July 25 2017 by Patrice Lee Onwuka
Cutting the Strings on Obamacare Enrollment Assistance July 24 2017 by Patrice Lee Onwuka
Not Even Death Stops a Government Check July 21 2017 by Patrice Lee Onwuka
Who Cares for the Caregivers? July 19 2017 by Patrice Lee Onwuka
College Diversity Officials Rake in Major Dough July 18 2017 by Patrice Lee Onwuka
DHS Hides Spending $3.6 Mil of Taxpayer Dollars on Pricey Conferences July 17 2017 by Patrice Lee Onwuka
Study: Marrying Before Having Kids is a Strong Path to Success for Millennials July 13 2017 by Patrice Lee Onwuka
$2 Mil NJ Welfare Fraud Exposes Holes in Our Social Safety Net July 7 2017 by Patrice Lee Onwuka
“WTF” is Silicon Valley’s Next Answer to the Democratic Party July 6 2017 by Patrice Lee Onwuka
Fraud Alert: Federal Free Phone, Internet Program Wastes $100 Mil Annually on Fake, Dead Enrollees July 3 2017 by Patrice Lee Onwuka
Cosmo Leaves Conservatives Off Their Short List of Female Presidential Candidates June 28 2017 by Patrice Lee Onwuka
Report: Seattle’s Minimum Wage Hike Gave Low-Wage Workers a $125 Monthly Pay Cut June 27 2017 by Patrice Lee Onwuka
Obama Comes Out to Bash Senate Repeal Bill June 23 2017 by Patrice Lee Onwuka
Maybe Profit Motivates Tech Companies More than Politics June 22 2017 by Patrice Lee Onwuka
Ivanka Trump Hits Capitol Hill about Paid Leave June 20 2017 by Patrice Lee Onwuka
Supreme Court Upholds Offensive Names as Free Speech June 20 2017 by Patrice Lee Onwuka
Silicon Valley CEOs Ignore Calls to Boycott Trump Tech Summit June 19 2017 by Patrice Lee Onwuka
What the Return of Pro-Net Neutrality Democrat Means for Internet Regs Rollback June 15 2017 by Patrice Lee Onwuka
Is the Federal Consumer Cop Asleep on the Job? June 15 2017 by Patrice Lee Onwuka
Obama Health Records Program Leaves Taxpayers on the Hook for Mispayments June 15 2017 by Patrice Lee Onwuka
Just in Time for July 4th New York State Greenlights Uber, Lyft June 9 2017 by Patrice Lee Onwuka
Filter, Don’t Pilfer June 8 2017 by Patrice Lee Onwuka
What Michelle Obama Gets Wrong About Self-Interest June 8 2017 by Patrice Lee Onwuka
Harvard Revokes Acceptances Over Online Comments June 6 2017 by Patrice Lee Onwuka
Bill Maher’s N-Word Episode June 5 2017 by Patrice Lee Onwuka
Hillary Clinton's Whine Tour Stops in Silicon Valley June 2 2017 by Patrice Lee Onwuka
Maryland Governor Shuts Down Paid Sick-Leave Bill May 26 2017 by Patrice Lee Onwuka
Chelsea Clinton Equates Child Marriage to Climate Change May 26 2017 by Patrice Lee Onwuka
Obamacare’s Death Spiral Claims Another Healthcare Insurer May 25 2017 by Patrice Lee Onwuka
Top 10 Unauthorized Federal Programs on the Chopping Block in Trump Budget May 25 2017 by Patrice Lee Onwuka
Supreme Court Ends Judge Shopping for Patent Trolls May 23 2017 by Patrice Lee Onwuka
State of Texas Trumps Austin over Uber, Lyft Regulations May 22 2017 by Patrice Lee Onwuka
Undoing Net Neutrality Starts Today May 18 2017 by Patrice Lee Onwuka
San Francisco May Stall Delivery Robots May 18 2017 by Patrice Lee Onwuka
Miss USA Stands by Her Comments – Good for Her May 17 2017 by Patrice Lee Onwuka
Miss USA Slammed for Saying Healthcare is a Privilege Rather than a Right May 15 2017 by Patrice Lee Onwuka
Don’t Be Tone Deaf on Hearing Aids May 11 2017 by Patrice Lee Onwuka
Grads Boo Betsy DeVos at Commencement May 11 2017 by Patrice Lee Onwuka
TV Comedian John Oliver Piles on to Save Obama Internet Rules May 10 2017 by Patrice Lee Onwuka
Automation Coming to a City near You May 9 2017 by Patrice Lee Onwuka
Your Zip code Is a Good Predictor for How Long You Live May 9 2017 by Patrice Lee Onwuka
Tech Bosses: Expect Significant Automation of Jobs by 2022 May 5 2017 by Patrice Lee Onwuka
Can Another Tech Squad to Transform How Washington Works? May 5 2017 by Patrice Lee Onwuka
Tech Founder to Ivanka Trump: Don’t Use My Story May 3 2017 by Patrice Lee Onwuka
Are Saving and Debt Repayment the New Normal for Americans? May 2 2017 by Patrice Lee Onwuka
This Immigrant is Showing Up to Work on May Day May 1 2017 by Patrice Lee Onwuka
FCC Announces Net Neutrality Reversal Plan April 27 2017 by Patrice Lee Onwuka
Copyright Office Reform Bill Passes House April 27 2017 by Patrice Lee Onwuka
FCC Expected to Kick Net Neutrality to the Curb April 26 2017 by Patrice Lee Onwuka
Delivery Robots Get Legislative Green Light in Two States April 25 2017 by Patrice Lee Onwuka
Harvard Study: Higher Minimum Wages Trigger Restaurant Closures April 24 2017 by Patrice Lee Onwuka
Not Done Rolling Back Washington’s Red Tape Yet April 19 2017 by Patrice Lee Onwuka
Three Celebrities Feeling the Pain on Tax Day April 18 2017 by Patrice Lee Onwuka
Female-Led FTC Takes Reducing Regulations Seriously April 18 2017 by Patrice Lee Onwuka
New York Pilots Free College Tuition Plan April 13 2017 by Patrice Lee Onwuka
Poll: Americans Comfortable with AI in Most--But Not All--Instances April 11 2017 by Patrice Lee Onwuka
No Phone Calls on Airplanes After All April 11 2017 by Patrice Lee Onwuka
Amazon to Hire 30,000 Part-time, Work-from-Home Jobs April 10 2017 by Patrice Lee Onwuka
Judge Blocks Seattle’s Plan to Unionize Uber April 7 2017 by Patrice Lee Onwuka
Stop the Misinformation on the Roll-Back of Privacy Rules April 5 2017 by Patrice Lee Onwuka
The Challenge of Counterfeit Drugs April 4 2017 by Patrice Lee Onwuka
Cali Lawmaker Wants to Push Gig-Economy Workers into Unions April 3 2017 by Patrice Lee Onwuka
FCC Reverses Federal Power Grab Over LifeLine Program (AKA ObamaPhones for the Internet) March 30 2017 by Patrice Lee Onwuka
Here’s How Uber is Boosting Diverse Applicants March 30 2017 by Patrice Lee Onwuka
Congress Scraps Obama-Era Privacy Rules March 30 2017 by Patrice Lee Onwuka
Should We Worry About Robots Replacing Workers? March 27 2017 by Patrice Lee Onwuka
Black Leaders Tell Trump What They Have to Lose March 23 2017 by Patrice Lee Onwuka
Congress to Free the Copyright Office from the Thumb of the Library of Congress March 23 2017 by Patrice Lee Onwuka
Why Everything from Dresses to Avocados May Get More Expensive March 22 2017 by Patrice Lee Onwuka
Trump, Clinton Campaigns Depended Upon Sharing Economy on the Campaign Trail March 21 2017 by Patrice Lee Onwuka
Before You Blame the Wage Gap, Check Your Attitude March 20 2017 by Patrice Lee Onwuka
Trump Hacks Away at the TSA March 20 2017 by Patrice Lee Onwuka
Trump Pumps the Brakes on Obama-Era Fuel Efficiency Regs March 16 2017 by Patrice Lee Onwuka
Students Push Back on Feminist Professor’s Indoctrination March 15 2017 by Patrice Lee Onwuka
President Trump: May Be Time to Say "You're Fired!" to Duplicative Agency Employees March 14 2017 by Patrice Lee Onwuka
Austin’s Struggle with Transportation After Uber, Lyft Ride Out of Town March 13 2017 by Patrice Lee Onwuka
Steve Case: American Workers Feeling Left Behind, Really Have Been Left Behind March 13 2017 by Patrice Lee Onwuka
Analogies Fly Over Net Neutrality March 9 2017 by Patrice Lee Onwuka
These are the Women A Day Without Women Hurts March 8 2017 by Patrice Lee Onwuka
Can Facebook’s New Tool Crack Down on “Fake News”? March 7 2017 by Patrice Lee Onwuka
Is Regulating the Internet a Good Idea? March 6 2017 by Patrice Lee Onwuka
Dr. Ben Carson Confirmed as HUD Head March 3 2017 by Patrice Lee Onwuka
Robots Green-Lighted to Deliver Your Packages March 2 2017 by Patrice Lee Onwuka
Three Key Messages to Black America from Trump’s Address March 1 2017 by Patrice Lee Onwuka
Reports: GM Lobbies to Keep Competing Self-Driving Tech Off the Road February 28 2017 by Patrice Lee Onwuka
New Self-driving Truck Company Speeds Up the Technology February 27 2017 by Patrice Lee Onwuka
Small Internet Companies Gain Regulatory Relief from Washington February 24 2017 by Patrice Lee Onwuka
Women Have a New Ally in Getting Them to Work February 24 2017 by Patrice Lee Onwuka
Federal Watchdog: Obama’s Techie Squad Flouted the Rules February 22 2017 by Patrice Lee Onwuka
Adulting School: Millennials Are Signing Up for Classes February 22 2017 by Patrice Lee Onwuka
Former AG Eric Holder Leading Internal Investigation at Uber February 21 2017 by Patrice Lee Onwuka
Whoopi Snubs the Mean Girls at New York Fashion Week in Defense of Tiffany Trump February 17 2017 by Patrice Lee Onwuka
Humana Calls It Quits on ObamaCare, Leaving One State in Trouble February 16 2017 by Patrice Lee Onwuka
Congress Opens the Door to Self-Driving Cars February 15 2017 by Patrice Lee Onwuka
Linda McMahon Confirmed to Head the SBA February 14 2017 by Patrice Lee Onwuka
Cabs Threaten to Halt Wheelchair Access Over Uber, Lyft February 14 2017 by Patrice Lee Onwuka
Trump Models: The Next Target in the Fashion World Purge February 13 2017 by Patrice Lee Onwuka
Senate Dems Come Out Swinging to Protect Washington’s Control of the Internet February 8 2017 by Patrice Lee Onwuka
A Surprise Stand for Competition Over Cronyism in Battle for NYC Streets? February 8 2017 by Patrice Lee Onwuka
Lifeline Internet Assistance Program (AKA Obamaphones for the Internet) Takes a Hit February 7 2017 by Patrice Lee Onwuka
Big Mac ATM’s, the Answer to $15 Minimum Wages? February 2 2017 by Patrice Lee Onwuka
New FCC Chairman Gets to Work Cutting Red Tape February 2 2017 by Patrice Lee Onwuka
Trump Transportation Secretary Chao Confirmed, Despite Democratic Protest February 1 2017 by Patrice Lee Onwuka
Cutting the Red Tap: President Trump Orders 2-for 1 Rule on Regulations January 31 2017 by Patrice Lee Onwuka
Chelsea Handler's Garbage-Pail Mouth is Now Shaming Melania Trump's English January 27 2017 by Patrice Lee Onwuka
Break out the Dow 20K Hats? January 27 2017 by Patrice Lee Onwuka
Apple Hit with Another Lawsuit over Distracted Driving January 25 2017 by Patrice Lee Onwuka
Getting American Workers Ready for Automation’s Coming Shake-Up January 24 2017 by Patrice Lee Onwuka
Uber Ponies Up $20M to Feds Over Driver Pay January 23 2017 by Patrice Lee Onwuka
Americans Aren’t Really Warming Up to Self-Driving Cars January 19 2017 by Patrice Lee Onwuka
The Government’s “Slant” on Trademarks Gets Challenged January 19 2017 by Patrice Lee Onwuka
Uber Sues Seattle to Block Drivers from Unionizing January 18 2017 by Patrice Lee Onwuka
Inauguration Reminds Us Why Home Sharing is a Win for Travelers January 17 2017 by Patrice Lee Onwuka
Jesse Jackson PUSHes Uber on Diversity Statistics January 13 2017 by Patrice Lee Onwuka
5 Times President Obama’s Rhetoric Didn’t Match His Kumbaya Message January 11 2017 by Patrice Lee Onwuka
Jenna Bush Microaggressess at the Golden Globes? January 10 2017 by Patrice Lee Onwuka
Rolling Back Obama’s Internet Privacy Rules January 9 2017 by Patrice Lee Onwuka
Update: City of San Diego Says Restaurants Can't Publicly Blame Surcharge on Minimum Wage Hike January 6 2017 by Patrice Lee Onwuka
San Diego Restaurants Slap Diners with Surcharges Thanks to Minimum Wage Increases January 6 2017 by Patrice Lee Onwuka
The Uber Hook-Up Effect January 5 2017 by Patrice Lee Onwuka
Christmas Eve Distracted Driving Fatality Could Trigger Government Action January 3 2017 by Patrice Lee Onwuka
Cali Regulators Drive Uber’s Self-Driving Cars Away December 27 2016 by Patrice Lee Onwuka
Will Seattle’s Driver Unionization be the End of Uber, Ridesharing? December 21 2016 by Patrice Lee Onwuka
Not Fake News: Some UVA Students Sign Fake Anti-Christmas Petition December 20 2016 by Patrice Lee Onwuka
Pinterest Misses Female Recruitment Quantity Quotas, But Hits on Quality December 19 2016 by Patrice Lee Onwuka
No Michelle Obama, “Hope” Doesn’t Start and End with Your Husband December 19 2016 by Patrice Lee Onwuka
Uber, San Francisco Regulators Crash Head-on over Self-Driving December 16 2016 by Patrice Lee Onwuka
More on the Shaming of Wonder Woman December 15 2016 by Patrice Lee Onwuka
Environmental Group Smears Black Beauty Products December 14 2016 by Patrice Lee Onwuka
San Francisco Mayor Sides with Airbnb December 12 2016 by Patrice Lee Onwuka
Airbnb Can’t Beat ‘Em, So Now They’re Lobbying ‘Em December 9 2016 by Patrice Lee Onwuka
The Supremes Side with Samsung Against Apple in High-Profile Patent Case December 7 2016 by Patrice Lee Onwuka
Cell Phones on the Road: A Serious Problem, but Do the Feds Need to Solve It? December 6 2016 by Patrice Lee Onwuka
Airbnb Took on the Big Apple and Lost December 5 2016 by Patrice Lee Onwuka
Obama’s Overtime Rule is Down, but Not Out December 2 2016 by Patrice Lee Onwuka
Taxpayers Will Forgive Billions More in Student Loan Debt December 2 2016 by Patrice Lee Onwuka
Uber Drivers Join Minimum Wage Protesters November 30 2016 by Patrice Lee Onwuka
Negative Online Reviews Get New Federal Protection November 30 2016 by Patrice Lee Onwuka
#GivingTuesday: the Hangover Cure for a Weekend of Spending November 29 2016 by Patrice Lee Onwuka
Some Maine Restaurant Workers Worried about Effects of Minimum Wage Hike November 28 2016 by Patrice Lee Onwuka
Judge Blocks Obama Workplace Overtime Rules November 23 2016 by Patrice Lee Onwuka
Pew: One in Four Americans Makes Bank through the Gig Economy November 21 2016 by Patrice Lee Onwuka
U.S. Small Businesses: Good News and Bad News November 21 2016 by Patrice Lee Onwuka
Arizona’s New Minimum Wage Packs a One-Two Punch for Nonprofits November 18 2016 by Patrice Lee Onwuka
Washington State Minimum Wage Passed and Childcare Costs Skyrocket November 17 2016 by Patrice Lee Onwuka
Hi, I’m Ben, Your Senator and Uber Driver! November 15 2016 by Patrice Lee Onwuka
Facebook Ends Multicultural Targeted Ads November 14 2016 by Patrice Lee Onwuka
Oprah’s Guarded Hope for the New President Triggers the Left November 14 2016 by Patrice Lee Onwuka
Star-Power Failed to Energize Millennials at the Polls November 10 2016 by Patrice Lee Onwuka
Mom-preneur Faces Charges for Selling Ceviche? November 9 2016 by Patrice Lee Onwuka
Uber is Back on the Road in Philly November 7 2016 by Patrice Lee Onwuka
Airbnb’s Self-Policing Strategy against Discrimination November 4 2016 by Patrice Lee Onwuka
Sanders and Warren Ignore that America is Better Off Now While Promoting Socialism • Evening Edit October 14 2019 by Patrice Lee Onwuka
Biden campaign plans to lose Iowa, New Hampshire, and Nevada • Rising October 11 2019 by Patrice Lee Onwuka
Is Warren trying to win black voters by floating Gillum as VP • Rising October 11 2019 by Patrice Lee Onwuka
US Businesses Should Stand Behind Hong Kong • Making Money October 9 2019 by Patrice Lee Onwuka
Left Leaning Outlets Turn on NYT Following Kavanaugh Hit Piece • Evening Edit September 23 2019 by Patrice Lee Onwuka
Partisan Party Politics Turns American Voters Off • Lou Dobbs Tonight September 18 2019 by Patrice Lee Onwuka
Bashing Billionaires Dissuades Everyone from Trying to Reach the Top • Making Money September 13 2019 by Patrice Lee Onwuka
Dems Have a Hard Case to Make Heading Into 2020 • Your World with Neil Cavuto September 9 2019 by Patrice Lee Onwuka
Dems Prioritize Gun Reform But Its All Talk • Evening Edit September 9 2019 by Patrice Lee Onwuka
Talking Tech: Is Being a "Big Company" a Bad Thing? • Making Money with Charles Payne September 6 2019 by Patrice Lee Onwuka
Media Needs to Find Balance Between Criticism and Support of President • Evening Edit September 3 2019 by Patrice Lee Onwuka
Democrats Continue to Focus on Emotion Over Fact: Biden and AOC • Trish Regan Primetime August 30 2019 by Patrice Lee Onwuka
Is the DNC rigging the debate rules? • Rising August 29 2019 by Patrice Lee Onwuka
Is South Carolina Biden's Hail Mary? • Rising August 29 2019 by Patrice Lee Onwuka
4 in 10 People Won't Trust the 2020 Election Results if Their Team Loses • Lou Dobbs Tonight August 28 2019 by Patrice Lee Onwuka
Taking Border Security Seriously with Approved Funding for The Wall • Evening Edit August 27 2019 by Patrice Lee Onwuka
Women Are Winning in This Economy • Coast to Coast August 22 2019 by Patrice Lee Onwuka
Language Police: In San Francisco and on Facebook • Lou Dobbs Tonight August 22 2019 by Patrice Lee Onwuka
Harry Reid Denounces Trajectory of Dem Party • Making Money with Charles Payne August 21 2019 by Patrice Lee Onwuka
Judge Trump’s actions, not words — and other commentary August 19 2019 by Patrice Lee Onwuka
Conservative commentator rips Shapiro over criticism of people with multiple jobs August 16 2019 by Patrice Lee Onwuka
How Will the Economy Effect the 2020 Conversation? • Coast to Coast August 15 2019 by Patrice Lee Onwuka
Israel Should Say "Thanks, But No Thanks" to Reps. Omar and Tlaib • Lou Dobbs Tonight August 15 2019 by Patrice Lee Onwuka
We Need to Act Now to Steer Away from Red Flags Ahead • Making Money August 14 2019 by Patrice Lee Onwuka
"In God We Trust" Is Important to Display in School • Lou Dobbs Tonight August 14 2019 by Patrice Lee Onwuka
Political Talking Points Stir Up Violent Threats Against SoulCycle Owner • Evening Edit August 9 2019 by Patrice Lee Onwuka
Pitting Consumers Against Businesses in the Name of Politics • Coast to Coast August 8 2019 by Patrice Lee Onwuka
Democratic Socialists Cannot Defeat Capitalism with Proper Pronouns and Complaints • Lou Dobbs August 6 2019 by Patrice Lee Onwuka
Don't pander to women; offer real opportunity August 1 2019 by Patrice Lee Onwuka
Bernie Ignores Legitimate Questions About his Health Care Plans • Evening Edit July 31 2019 by Patrice Lee Onwuka
The Washington Post Plays Scapegoat for Those Still Hung Up on 2016 Election • Lou Dobbs Tonight July 30 2019 by Patrice Lee Onwuka
Food Stamps Cut Because Booming Economy Means Less People Need Them • Fox & Friends First July 24 2019 by Patrice Lee Onwuka
The Squad Tries Pushing the Democrats Further Left Over Israel • Evening Edit July 24 2019 by Patrice Lee Onwuka
$15 Minimum Wage Robs Women of Jobs, Opportunity, Economic Mobility July 18 2019 by Patrice Lee Onwuka
"Squad" Pushes Democrat Party Closer to Socialism • Coast to Coast July 17 2019 by Patrice Lee Onwuka
"Woke Activism" is No Way to Get Things Done in Congress • Fox & Friends First July 15 2019 by Patrice Lee Onwuka
Cory Gardner, the women’s vote and religion: Western Conservative Summit takeaways July 14 2019 by Patrice Lee Onwuka
Democrats Have Placed All Their Eggs in the Identity Politics Basket • Evening Edit July 11 2019 by Patrice Lee Onwuka
AOC Needs to Tread Lightly Instead of Pointing Fingers at House Leadership • Your World July 11 2019 by Patrice Lee Onwuka
Why Restaurant Workers are Rising Up to Save Tipped Wages July 9 2019 by Patrice Lee Onwuka
Women's World Cup Champions Demand Equal Pay, Do the Numbers Add Up? • After The Bell July 8 2019 by Patrice Lee Onwuka
The Folly of Demanding Amazon’s Tax Returns • Liberty Watch Radio July 7 2019 by Patrice Lee Onwuka
Democrats are Obsessed Over the Past as the Candidates Take Aim at Each Other • Making Money July 5 2019 by Patrice Lee Onwuka
Supreme Court Reaches Verdict on 2020 Census Question • Your World with Neil Cavuto June 27 2019 by Patrice Lee Onwuka
Democrats Ignore Booming Economy and Foreshadow Recession • Evening Edit June 25 2019 by Patrice Lee Onwuka
Economists Determine the Value of "Free" Social Media Apps • Making Money June 24 2019 by Patrice Lee Onwuka
Race is a Central Issue for 2020, Biden is Learning the Hard Way • Coast to Coast June 20 2019 by Patrice Lee Onwuka
Hearing on Reparations Shows Just How Complicated This Issue Is • Trish Regan Primetime June 19 2019 by Patrice Lee Onwuka
President Trump Prioritizes Legal Immigrants During Border Crisis • Lou Dobbs Tonight June 18 2019 by Patrice Lee Onwuka
Lets Take an Objective Look at the Russian Interference Allegations • PoliticsNation June 15 2019 by Patrice Lee Onwuka
Liberals Distract Voters From Booming Economy with Social Issues • Lou Dobbs Tonight June 14 2019 by Patrice Lee Onwuka
Why Kamala Harris’ ‘Equal Pay’ Proposal Will Hurt, Not Help Women June 13 2019 by Patrice Lee Onwuka
Republicans and Democrats at odds on overtime pay June 13 2019 by Patrice Lee Onwuka
Deep Fake Videos Can Have Dangerous Repercussions • Evening Edit June 12 2019 by Patrice Lee Onwuka
Bernie Sanders Bashes Walmart Execs Claiming Minimum Wage Isn't High Enough • Coast to Coast June 5 2019 by Patrice Lee Onwuka
Mandated Paid Time Off Is Not Only Bad for Most Businesses, It's Bad for Many Women June 5 2019 by Patrice Lee Onwuka
Democrats Throw Money at Homelessness But the Situation Still Gets Worse, Why? • Lou Dobbs Tonight June 5 2019 by Patrice Lee Onwuka
Stossel: The Paid Leave Fairy Tale • Reason TV June 4 2019 by Patrice Lee Onwuka
Crisis at the Border and Draining the Swamp, Trust Trump to Create Change • Making Money May 31 2019 by Patrice Lee Onwuka
Kamala Harris’ New Proposal to Punish Companies Renews Wage Gap Debate • Bold Politics May 24 2019 by Patrice Lee Onwuka
Conflict in D.C. Does Effect Markets, But Consumers Continue to Spend • Coast to Coast May 23 2019 by Patrice Lee Onwuka
The Gender Wage Gap and What You Can Do About It May 22 2019 by Patrice Lee Onwuka
Top Dems Blow Any Chance of Bipartisan Reform • Evening Edit May 22 2019 by Patrice Lee Onwuka
Women's Organization Announces The 2019 Empowered Woman of the Year May 21 2019 by Patrice Lee Onwuka
Kamala Harris Threatens to Fine Businesses that Contribute to the "Pay Gap" • Fox & Friends May 21 2019 by Patrice Lee Onwuka
Low Birth Rates Could Have Devastating Economic Impacts • Fox & Friends May 16 2019 by Patrice Lee Onwuka
Policy analyst on falling birth rates: Rhetoric from the left contributing to 'change in norms' May 16 2019 by Patrice Lee Onwuka
Sanctuary Cities Putting Illegal Immigrants Ahead of Citizens • Lou Dobbs Tonight May 8 2019 by Patrice Lee Onwuka
Trump Should Look to Private Sector for Federal Reserve Board Nominees • Coast to Coast May 2 2019 by Patrice Lee Onwuka
Every Aspect of the Economy is Thriving From Jobs, Wages, To Taxes• Fox & Friends First April 29 2019 by Patrice Lee Onwuka
Bernie Struggles to Win Over Black Women • Evening Edit April 25 2019 by Patrice Lee Onwuka
Patrice Onwuka on Plastic Bag Bans, Net Neutrality and Michelle Obama • Americhicks April 23 2019 by Patrice Lee Onwuka
Many Americans Don't Care About the Mueller Report • Cavuto Live April 20 2019 by Patrice Lee Onwuka
Obama Playbook Will Not Be Enough to Get Joe Biden in the White House • Fox & Friends April 20 2019 by Patrice Lee Onwuka
Mueller Report Finally Available: What did it say and what is next? • WAMU April 18 2019 by Patrice Lee Onwuka
Opportunity Zones Create Economic Prosperity • Making Money with Charles Payne April 17 2019 by Patrice Lee Onwuka
Left Tries Desperately To Keep Collusion Narrative Alive • Coast to Coast April 15 2019 by Patrice Lee Onwuka
As support for reparations grow, so does pushback from some black Americans April 12 2019 by Patrice Lee Onwuka
Democrats Are Selective When Deciding Who is Innocent or Guilty • Fox & Friends Saturday April 6 2019 by Patrice Lee Onwuka
Being Fiscally Conservative Includes Being Smart on All Aspects of the Economy • Coast to Coast April 3 2019 by Patrice Lee Onwuka
Don't Fall for the Equal Pay Day Myth • Larry O'Connor Show April 2 2019 by Patrice Lee Onwuka
Presidential Hopefuls Playing Politics with Joe Biden's Victims • Evening Edit April 1 2019 by Patrice Lee Onwuka
Joe Biden's 2020 Doom • Cheddar Politics April 1 2019 by Patrice Lee Onwuka
Marco Rubio's New Family Leave Bill is a Budget Neutral Conservative Plan • Coast to Coast March 27 2019 by Patrice Lee Onwuka
The gender pay gap still exists - but it's shrinking, according to a new study March 27 2019 by Patrice Lee Onwuka
Millions of American off food stamps under President Trump • OANN March 23 2019 by Patrice Lee Onwuka
The Electoral College Matters, and Here's Why • The Evening Edit March 20 2019 by Patrice Lee Onwuka
Threats to Drag Out Investigation Despite No Evidence Of Collusion • The Evening Edit March 13 2019 by Patrice Lee Onwuka
A Legislative Unicorn: Paid Family Leave Without New Taxes or Entitlements March 12 2019 by Patrice Lee Onwuka
Congress considers parental leave programs March 12 2019 by Patrice Lee Onwuka
The Ivanka Trump effect: Why Republicans are now championing paid family leave, and what their new proposal looks like March 12 2019 by Patrice Lee Onwuka
Joni Ernst, Mike Lee roll out conservative paid parental leave idea March 12 2019 by Patrice Lee Onwuka
Raising the Topic of Paid Parental Leave March 12 2019 by Patrice Lee Onwuka
Republicans Propose Plan to Let Parents Use Social Security for Paid Family Leave After Having a Child March 12 2019 by Patrice Lee Onwuka
GOP senators unveil paid parental leave proposal March 12 2019 by Patrice Lee Onwuka
Support Choices That Women Make When Looking at Gender Pay Gap • Making Money with Charles Payne March 8 2019 by Patrice Lee Onwuka
Trump Previews 2020 in CPAC Speech • Fox and Friends First March 4 2019 by Patrice Lee Onwuka
Consumer Confidence Bouncing Back as Trump Looks Ahead to 2020 • Coast to Coast March 4 2019 by Patrice Lee Onwuka
Pelosi Should Second Guess New Member's Calls for Trump Impeachment • The Evening Edit February 27 2019 by Patrice Lee Onwuka
AOC Lives in Luxury Housing in D.C. Despite Her Views on Affordable Housing • Fox and Friends First February 21 2019 by Patrice Lee Onwuka
Bernie Attacks Someone Who Achieved the American Dream • Making Money with Charles Payne February 20 2019 by Patrice Lee Onwuka
Bernie Sanders Continues to Misrepresent the Reality of Socialism • The Evening Edit February 19 2019 by Patrice Lee Onwuka
Meet the Women Who Protested the Women’s March January 21 2019 by Patrice Lee Onwuka
Trump Putting Border Security on the Table with DACA Extension • America's News Headquarters January 19 2019 by Patrice Lee Onwuka
Women's March is Not Inclusive of All Ideas • Fox & Friends January 19 2019 by Patrice Lee Onwuka
USPS Relies on Amazon: What this means for consumers • Your World with Neil Cavuto December 5 2018 by Patrice Lee Onwuka
How Will Markets React to a Potential Trade Deal with China? • Coast to Coast November 29 2018 by Patrice Lee Onwuka
Streisand accuses Trump of misogyny while liberals turn on their own November 28 2018 by Patrice Lee Onwuka
What Pete Davidson’s SNL Apology Could Teach Us About Civility • Bold Politics November 16 2018 by Patrice Lee Onwuka
Is Amazon Guilty of Taking Part In Corporate Welfare? • The Evening Edit November 14 2018 by Patrice Lee Onwuka
'Economic damage' predicted after city levies big tax on hi-tech firms November 13 2018 by Patrice Lee Onwuka
Markets React to Midterm Election Results • Coast to Coast November 12 2018 by Patrice Lee Onwuka
Volatile Markets Will Only Marginally Influence Midterms • The Evening Edit October 26 2018 by Patrice Lee Onwuka
PETA Claims Milk is Racist • Trish Regan Primetime October 23 2018 by Patrice Lee Onwuka
How Will Booming Economy Be Affected by The Fed? • Coast to Coast October 17 2018 by Patrice Lee Onwuka
Kanye Brings Attention to Real Economic Issues • Coast to Coast October 11 2018 by Patrice Lee Onwuka
Will Kavanaugh Confirmation Drive Women Away from the GOP? Not Likely October 8 2018 by Patrice Lee Onwuka
Anti-Kavanaugh Harassment Tactics Overlooked by the Left • Coast to Coast October 4 2018 by Patrice Lee Onwuka
Statement on #CancelKavanaugh Protest: Activists Use Dr. Ford to Exploit Emotion Over a Deeply Personal Issue October 4 2018 by Patrice Lee Onwuka
Republican Women Explain Why They Stand By Brett Kavanaugh More Than Ever October 3 2018 by Patrice Lee Onwuka
Women Want Kavanaugh Confirmed if FBI Finds No Corroborating Evidence • FBN am October 3 2018 by Patrice Lee Onwuka
A Tale of Two Cities: A Snapshot of Washington D.C. On the Historic Kavanaugh-Ford Hearing Day September 27 2018 by Patrice Lee Onwuka
FBI Investigation Was an Ongoing Distraction During Hearings • After the Bell September 27 2018 by Patrice Lee Onwuka
'There's No Presumption of Innocence': Women Rally Both for and Against Kavanaugh September 27 2018 by Patrice Lee Onwuka
Dems Would Love for Trump to Fire Rosenstein • Fox & Friends First September 25 2018 by Patrice Lee Onwuka
Republicans Have Gone Out of Their Way to Try to Hear Blasey • Coast to Coast September 21 2018 by Patrice Lee Onwuka
Jacques: Sexism is a losing strategy September 14 2018 by Patrice Lee Onwuka
Good Trade Relations with China is Good for the Economy • Coast to Coast September 12 2018 by Patrice Lee Onwuka
Will Reforming SNAP Benefit Americans? • Bold Politics September 7 2018 by Patrice Lee Onwuka
Motivations Behind Trying to Flip a Russian Oligarch • Fox & Friends First September 3 2018 by Patrice Lee Onwuka
More Than Ever, Millennials Are Taking Care of Their Aging Family Members • Bold Life August 24 2018 by Patrice Lee Onwuka
Trump's Commitment to Diversity in the White House Continues After Omarosa • Andrew Wilkow Show August 22 2018 by Patrice Lee Onwuka
Statement: IWF Applauds Roll Back of Clean Power Plan August 22 2018 by Patrice Lee Onwuka
Omarosa’s Antics Won't Undermine Trump’s Progress for Black Americans • Afternoons with Cliff Kelley August 21 2018 by Patrice Lee Onwuka
NYT Publishes Pure Speculation on Mueller Investigation • Fox & Friends First August 20 2018 by Patrice Lee Onwuka
America IS Great: a lesson from real Immigrants • Fox & Friends August 18 2018 by Patrice Lee Onwuka
Harley-Davidson Staying in U.S. is Huge Victory • Coast to Coast August 17 2018 by Patrice Lee Onwuka
Is there a racial gender pay gap? • Bold Politics August 10 2018 by Patrice Lee Onwuka
Ocasio-Cortez Forgets Socialism Didn't Work in South America • Your World with Neil Cavuto August 9 2018 by Patrice Lee Onwuka
Rubio-Wagner family leave bill would draw from Social Security August 7 2018 by Patrice Lee Onwuka
Explaining the Economic Security for New Parents Act • KDKA August 3 2018 by Patrice Lee Onwuka
Rubio's New Paid Leave Bill is Great for Women • Fox & Friends First August 2 2018 by Patrice Lee Onwuka
Bernie Sanders "Medicare for All" plan would be a disaster • Your World with Neil Cavuto July 31 2018 by Patrice Lee Onwuka
How will new GDP numbers influence the midterm elections • Coast to Coast July 30 2018 by Patrice Lee Onwuka
New Bill Aims to Extend Trump Tax Cuts Beyond 2025 • Fox & Friends First July 25 2018 by Patrice Lee Onwuka
Sessions prepares students for diverse opinions at college • Making Money with Charles Payne July 24 2018 by Patrice Lee Onwuka
Student loan debt saddling non-saving Millennials July 24 2018 by Patrice Lee Onwuka
Only 4.9 Percent of People Have Two Jobs • Fox & Friends First July 19 2018 by Patrice Lee Onwuka
Companies thinking about intellectual theft when dealing with China • Coast to Coast July 18 2018 by Patrice Lee Onwuka
Cyber Security Needs to be Taken Seriously During Trump-Putin Summit • FBN am July 16 2018 by Patrice Lee Onwuka
What Do You Think Of Seattle's Plastic Straw Ban? • Bold Life July 6 2018 by Patrice Lee Onwuka
Hopeful About North Korean Cooperation • FBN am July 6 2018 by Patrice Lee Onwuka
#133 Reforms needed for children's television July 2 2018 by Patrice Lee Onwuka
How will Supreme Court nominations effect the primaries? • Coast to Coast June 29 2018 by Patrice Lee Onwuka
Trump is no excuse for intimidation of women June 28 2018 by Patrice Lee Onwuka
Protesters Want Media Attention, Not Policy Change • Your World with Neil Cavuto June 22 2018 by Patrice Lee Onwuka
Immigration bills will be hard to pass, but we can't ignore this issue • FBN AM June 20 2018 by Patrice Lee Onwuka
We should be concerned that foreign agents had access to Hillary's emails • Fox & Friends First June 15 2018 by Patrice Lee Onwuka
Free Trade Without Free Riders • Coast to Coast June 7 2018 by Patrice Lee Onwuka
Democrats Playing Politics in Primaries • Making Money with Charles Payne June 4 2018 by Patrice Lee Onwuka
IWF Statement on New Steel and Aluminum Tariffs May 31 2018 by Patrice Lee Onwuka
Trump had good reason to pull out of meeting with North Korea • Making Money with Charles Payne May 24 2018 by Patrice Lee Onwuka
Should Medical Marijuana Be Allowed in Classrooms? • Fox & Friends First May 21 2018 by Patrice Lee Onwuka
Media Bias After They Refuse to Accept Trump's Corrected Statement • Your World with Neil Cavuto May 17 2018 by Patrice Lee Onwuka
Lower Birth Rates: Student Debt, Societal Change, Technological Advances • The Intelligence Report May 17 2018 by Patrice Lee Onwuka
China's Relationship with North Korea Could Make All The Difference • FBN am May 16 2018 by Patrice Lee Onwuka
#127 Questioning the Status Quo: Black voters don't owe their vote to either party May 14 2018 by Patrice Lee Onwuka
Were there problems with Cohen's payments? • Coast to Coast May 10 2018 by Patrice Lee Onwuka
Removing "In God We Trust" to be Politically Correct • Fox & Friends First May 7 2018 by Patrice Lee Onwuka
Proof Mueller is Fishing for Evidence • FBN am May 7 2018 by Patrice Lee Onwuka
We Want to Ensure a Legitimate and Lawful Immigration Process • FBN am April 26 2018 by Patrice Lee Onwuka
Nancy Pelosi Chokes on "Crumbs" Comment Because It Just Isn't True • Coast to Coast April 25 2018 by Patrice Lee Onwuka
#123 Education Savings Accounts for Military Families Can Make All the Difference April 23 2018 by Patrice Lee Onwuka
Why are so many young adults choosing to stay at home? • BoldTV April 20 2018 by Patrice Lee Onwuka
Gov. Brown is Choosing Sanctuary over Safety • Risk & Reward April 19 2018 by Patrice Lee Onwuka
Comey has made enemies on both sides of the aisle • Risk & Reward April 19 2018 by Patrice Lee Onwuka
Bias training won't do much at Starbucks • Intelligence Report with Trish Reagan April 19 2018 by Patrice Lee Onwuka
Tax Cuts Will Play Major Role in Midterms • Coast to Coast April 5 2018 by Patrice Lee Onwuka
New Survey: What would Americans do for a 10% raise? • Fox & Friends First April 5 2018 by Patrice Lee Onwuka
Trump to rescind spending with a maneuver Clinton used nearly 20 years ago • FBN:am April 5 2018 by Patrice Lee Onwuka
Citizenship Question MUST be Answered Truthfully • Cavuto Live April 2 2018 by Patrice Lee Onwuka
#118 New Amendment Provides Protection Against the Discrimination of Pregnant Women April 2 2018 by Patrice Lee Onwuka
On the New Spending Bill: Entitlements Drive the National Debt • Risk & Reward March 23 2018 by Patrice Lee Onwuka
Regulations will Hinder Innovation on Social Media • Risk & Reward March 23 2018 by Patrice Lee Onwuka
White House Millennials Conference to Address Economy, Free Speech, and Opioids March 18 2018 by Patrice Lee Onwuka
In the #MeToo era, young conservative women look for their spot March 16 2018 by Patrice Lee Onwuka
Shake Ups in White House Happening for a Reason • FBN AM March 15 2018 by Patrice Lee Onwuka
Dems Will Not Continue to Embrace Middle America • Coast to Coast March 14 2018 by Patrice Lee Onwuka
We Don't Want to Abandon Free Trade • Cavuto Live March 10 2018 by Patrice Lee Onwuka
GOP takes on paid family leave March 10 2018 by Patrice Lee Onwuka
Issues in California are a Classic Case of Federalism • Risk & Reward March 9 2018 by Patrice Lee Onwuka
A Trade War is Going to Undermine Current Economic Progress • Coast to Coast March 5 2018 by Patrice Lee Onwuka
#113 What You Don't Know About Immigrants: A real immigrant's story March 2 2018 by Patrice Lee Onwuka
A conservative solution to paid leave • The National Discourse Podcast February 27 2018 by Patrice Lee Onwuka
CNN Pushes Agenda at Townhall • Risk & Reward February 23 2018 by Patrice Lee Onwuka
Americans Recognize the 2nd Amendment is Important to Protect • Coast to Coast February 20 2018 by Patrice Lee Onwuka
Republicans Produced Plan, Waiting for Action Across the Aisle • FBN AM February 13 2018 by Patrice Lee Onwuka
#MeToo and Working Women • PBS To The Contrary February 10 2018 by Patrice Lee Onwuka
Fundamentals of Our Economy Are Strong • Coast to Coast February 8 2018 by Patrice Lee Onwuka
Republicans Tired of Partisan Bickering • Coast to Coast January 31 2018 by Patrice Lee Onwuka
Unions Losing Battle Against Inevitable Future • The Intelligence Report January 25 2018 by Patrice Lee Onwuka
Did Schumer Cave on Gov Shut Down? • FBN am January 23 2018 by Patrice Lee Onwuka
Dems ‘Big Risk’ Not Worth It • Your World January 22 2018 by Patrice Lee Onwuka
Media Attacks Trump's Doctor • Risk & Reward January 19 2018 by Patrice Lee Onwuka
The Left Criticizing Tax Plan and Immigration • Risk & Reward January 12 2018 by Patrice Lee Onwuka
Concerns on Trade with China • Coast to Coast January 10 2018 by Patrice Lee Onwuka
Weighing in on Trump vs. Bannon • FBN AM January 5 2018 by Patrice Lee Onwuka
U.N. Funding Cut Good for Women • Forbes on Fox December 29 2017 by Patrice Lee Onwuka
Next Moves for the GOP • Coast to Coast December 26 2017 by Patrice Lee Onwuka
Saving Money After the Holidays • Fox & Friends First December 26 2017 by Patrice Lee Onwuka
Senate Passes Tax Bill • FBN AM December 20 2017 by Patrice Lee Onwuka
Are Black Women Leaving The Democratic Party to Become Independents? December 19 2017 by Patrice Lee Onwuka
Final GOP Tax Bill • Risk & Reward December 15 2017 by Patrice Lee Onwuka
Statement: Unnecessary internet regulation no more, FCC right to overturn net neutrality rules December 14 2017 by Patrice Lee Onwuka
Calls for Conyers to Resign • Risk & Reward Pt. 2 December 1 2017 by Patrice Lee Onwuka
Steinle's Killer Acquitted • Risk & Reward Pt. 1 December 1 2017 by Patrice Lee Onwuka
FCC Net Neutrality Vote Looms: How could things change? • The Big Picture December 1 2017 by Patrice Lee Onwuka
Time for Transparency: Taxpayer dollars used to protect Congressional misbehavior • Coast to Coast November 30 2017 by Patrice Lee Onwuka
More Bang for Your Buck • Fox & Friends First November 30 2017 by Patrice Lee Onwuka
Are some Dems willing to sacrifice protections for women to hold onto power? • Intelligence Report November 28 2017 by Patrice Lee Onwuka
Federal Judge blocks Trump's EO on Sanctuary Cities: Is Trump at a disadvantage? • Bulls & Bears November 25 2017 by Patrice Lee Onwuka
Has NFL commissioner lost control of the hemorrhaging league? • Bulls & Bears November 25 2017 by Patrice Lee Onwuka
Black Friday protests dwindle exposing this uncomfortable truth • Bulls & Bears November 25 2017 by Patrice Lee Onwuka
Sexual harassment is wrong no matter when it occurred and by whom • Varney & Co. November 24 2017 by Patrice Lee Onwuka
Bernie Sanders Blatantly Gives Bill Clinton, Al Franken a Pass on Sexual Harassment November 20 2017 by Patrice Lee Onwuka
There's Nothing Glamorous about “Auntie" Maxine Waters & Her “Impeach Him!” Chant November 17 2017 by Patrice Lee Onwuka
Twitter cracking down on Verified accounts • Fox & Friends First November 17 2017 by Patrice Lee Onwuka
'Saturday Night Live' says DNC is old and out of touch • Risk & Reward November 13 2017 by Patrice Lee Onwuka
Tax reform push: Will there be compromise? • FBN:AM November 13 2017 by Patrice Lee Onwuka
Are tech companies truly neutral platforms or do they reflect bias? • Fox & Friends First November 3 2017 by Patrice Lee Onwuka
Statement: GOP Tax Bill is a Win for Women November 2 2017 by Patrice Lee Onwuka
CNBC Slams DNC Chair Tom Perez, 'Get Off The Talking Points' On GOP Tax Plan November 2 2017 by Patrice Lee Onwuka
We cannot choose our history but we can choose not to repeat it • Risk & Reward October 31 2017 by Patrice Lee Onwuka
We're seeing the waning days of the NFL protests • Risk & Reward October 31 2017 by Patrice Lee Onwuka
This tax reform plan will help all workers • FBN:AM October 30 2017 by Patrice Lee Onwuka
West Wing Reads for 10/30/17 October 30 2017 by Patrice Lee Onwuka
Will any democrats get on board with tax reform? • FBN AM October 26 2017 by Patrice Lee Onwuka
What role is Bannon playing outside of the White House? • MSNBC Live October 23 2017 by Patrice Lee Onwuka
Podcast #98 Why sexual assault statistics on college campuses are misleading October 19 2017 by Patrice Lee Onwuka
Will new Trump/McConnell bromance last to get agenda through? • FBN AM October 17 2017 by Patrice Lee Onwuka
Hillary caring about "women's issues" a sham? • The Intelligence Report October 16 2017 by Patrice Lee Onwuka
More sexual harrassment allegations come out in Hollywood • Risk & Reward October 13 2017 by Patrice Lee Onwuka
Wait–Are Black Women Leaving The Democratic Party? October 11 2017 by Patrice Lee Onwuka
Eminem bashes Trump in new music video, but does it matter? • Coast To Coast October 11 2017 by Patrice Lee Onwuka
Statement: Abandoning The Clean Power Plan: A Destructive Regulatory Package October 10 2017 by Patrice Lee Onwuka
These four GOP Senators won't vote for Graham-Cassidy • FBN AM September 26 2017 by Patrice Lee Onwuka
These celebrities are joining in on the NFL anthem protests... • Risk & Reward September 26 2017 by Patrice Lee Onwuka
This sport is standing up for the National Anthem... • Risk & Reward September 25 2017 by Patrice Lee Onwuka
Does Graham-Cassidy healthcare bill have a chance? • FBN AM September 21 2017 by Patrice Lee Onwuka
Emmy's and NFL in ratings slide due to politics • Risk & Reward September 19 2017 by Patrice Lee Onwuka
A new left-wing strategy against Trump September 18 2017 by Patrice Lee Onwuka
Can Trump pull bi-partisan support for tax reform? • FBN AM September 13 2017 by Patrice Lee Onwuka
Is there an opportunity for bi-partisanship with recent devastations? • Coast To Coast September 11 2017 by Patrice Lee Onwuka
White House shake up doesn't mean the agenda stops • Risk & Reward August 18 2017 by Patrice Lee Onwuka
Let's consider moving Confederate monuments to museums • FBN AM August 17 2017 by Patrice Lee Onwuka
Trump holds Congress' feet to the fire on health care • Coast To Coast August 11 2017 by Patrice Lee Onwuka
Why diversity quotas may not be a good thing for companies • Intelligence Report August 7 2017 by Patrice Lee Onwuka
Left trying to label 'Death Wish' alt-right • Risk & Reward August 7 2017 by Patrice Lee Onwuka
Podcast #90: How the Internet is Giving Women Back Their Time August 2 2017 by Patrice Lee Onwuka
Will those who voted against repeal face tough constituent questions? • FBN AM July 28 2017 by Patrice Lee Onwuka
Brave move by John McCain with healthcare vote? • FBN AM July 28 2017 by Patrice Lee Onwuka
Jeff Sessions is yet another distraction from Trump agenda • Your World July 27 2017 by Patrice Lee Onwuka
Is getting a better education for your children racist? • Risk & Reward July 24 2017 by Patrice Lee Onwuka
Why democrats have failed to come up with plan to make Obamacare better • FBN AM July 20 2017 by Patrice Lee Onwuka
Should Congress forget healthcare repeal and move onto tax reform? • The Intelligence Report July 18 2017 by Patrice Lee Onwuka
Will Congress work through August recess? • Coast To Coast July 11 2017 by Patrice Lee Onwuka
Was it wrong for Ivanka to sit in at the G20? • Your World July 10 2017 by Patrice Lee Onwuka
Would media act differently if it was Chelsea Clinton at the G20? • Risk & Reward July 10 2017 by Patrice Lee Onwuka
Is the Trump administration good for the economy? • Fox 5 DC July 7 2017 by Patrice Lee Onwuka
Is Trump's agenda back on track? • FBN AM June 29 2017 by Patrice Lee Onwuka
Will the healthcare bill pass before July 4 recess? • FBN AM June 29 2017 by Patrice Lee Onwuka
People would be better served if we had a real healthcare market place • Risk & Reward June 27 2017 by Patrice Lee Onwuka
Black women work hard but can’t get ahead. This expert says conservatives have the solution. June 19 2017 by Patrice Lee Onwuka
Is Trump hurting himself when he tweets? • Coast To Coast June 7 2017 by Patrice Lee Onwuka
This is why you shouldn't jump on Larry Hogan for vetoing paid sick leave bill • Larry O'Connor Show May 26 2017 by Patrice Lee Onwuka
How much damage has been done to the Trump administration by the media? • FBN AM May 24 2017 by Patrice Lee Onwuka
Miss USA Slammed For Saying Healthcare Is A Privilege Rather Than A Right • Marc Cox May 16 2017 by Patrice Lee Onwuka
One Black Conservative Made It On Liberal List Of Beautiful Black Women April 25 2017 by Patrice Lee Onwuka
Essence’s “100 Woke Women” List: Where Are All The Conservatives? April 20 2017 by Patrice Lee Onwuka
Do Voters Actually Care About Trump's Tax Returns? • Coast To Coast April 17 2017 by Patrice Lee Onwuka
PBS teaching ISIS sympathy • Risk & Reward April 14 2017 by Patrice Lee Onwuka
Ivanka Trump Accepts Role as White House Advisor • Coast to Coast March 30 2017 by Patrice Lee Onwuka
Ryan Pulls Healthcare Bill Before Vote • MSNBC Live March 28 2017 by Patrice Lee Onwuka
Debate over Cost of Healthcare Overhaul ahead of CBO Score • Coast to Coast March 14 2017 by Patrice Lee Onwuka
A Day without a Woman • Making Money March 9 2017 by Patrice Lee Onwuka
Any Momentum Left from President Trump's Address? • MSNBC Live March 5 2017 by Patrice Lee Onwuka
Political double-speak: Who's line is it? • Risk & Reward February 23 2017 by Patrice Lee Onwuka
CNN may suffer from ‘PESD’ post-election stress disorder • Risk & Reward February 23 2017 by Patrice Lee Onwuka
WWE's Linda McMahon Confirmed To Head The Small Business Administration • Steve Gruber February 17 2017 by Patrice Lee Onwuka
Vice President Pence addressing right-to-life marchers in D.C. • Coast to Coast January 27 2017 by Patrice Lee Onwuka
Raising Minimum Wage 'Not Worth It' January 23 2017 by Patrice Lee Onwuka
Have Race Relations Improved Under Obama Presidency? • Tipping Point January 14 2017 by Patrice Lee Onwuka
If Republicans rush to repeal ObamaCare without a strategy to provide immediate relief to its victims, the ongoing collapse of insurance markets will continue • Coast To Coast January 9 2017 by Patrice Lee Onwuka
Sanctions A Political Move By Obama? • Risk & Reward December 30 2016 by Patrice Lee Onwuka
Be Careful Jumping On Consensus Bandwagon • Coast To Coast December 23 2016 by Patrice Lee Onwuka
Irony: Conway Facing Work-Life-Balance Criticism From Left After Accepting Position • Your World December 22 2016 by Patrice Lee Onwuka
Are Election Results Everyone's Fault But Democrats? • Coast To Coast December 9 2016 by Patrice Lee Onwuka
Controversy Over Trump's Stocks-But Do Americans Care? • Your World December 7 2016 by Patrice Lee Onwuka
Oprah's Message Of Hope Triggers The Left • Garrison November 17 2016 by Patrice Lee Onwuka
Is There A Double Standard With Protests Around Country? • Coast To Coast November 14 2016 by Patrice Lee Onwuka
AirBnB's Growing List Of Enemies + Halloween's Cultural Appropriation Police • Garrison October 20 2016 by Patrice Lee Onwuka
Forging a Generation of Opportunity October 20 2016 by Patrice Lee Onwuka
Political Correctness Plagues Halloween • Tipping Point October 18 2016 by Patrice Lee Onwuka
Democrats Relationship With Media In Question After Wikileaks Dump • Coast To Coast October 14 2016 by Patrice Lee Onwuka
Is IQ or EQ More Important In The Presidential Debates? • Your World September 20 2016 by Patrice Lee Onwuka
Are Self-Driving Cars A Good Idea + AirBnB Doesn't Drive Rent Higher • Garrison September 15 2016 by Patrice Lee Onwuka
Podcast #51 College Students: Don't Major In Debt! September 15 2016 by Patrice Lee Onwuka
Mylan's EpiPen Monopoly Created By Big Government • Tipping Point September 13 2016 by Patrice Lee Onwuka
Will Hillary Send More Troops Back Into Middle East? • Risk & Reward September 9 2016 by Patrice Lee Onwuka
Ad Spoofs 9/11 Attack • Risk & Reward September 9 2016 by Patrice Lee Onwuka
Mylan & Big Government On Hook For Rising EpiPen Costs • Your World September 2 2016 by Patrice Lee Onwuka
Did Kaepernick Right His Protest By Kneeling During Anthem? • Risk & Reward September 2 2016 by Patrice Lee Onwuka
Georgetown Offers Preferential Admission Status To Descendants Of Slaves • Risk & Reward September 1 2016 by Patrice Lee Onwuka
Labor Force Participation Rate Reaches 38 Year Low • Tipping Point August 5 2016 by Patrice Lee Onwuka
Can Trump Recover From His Comments About Slain Soldier's Parents? • Risk & Reward August 1 2016 by Patrice Lee Onwuka
Can Trump Close The Gap With Minorities? • Tipping Point June 10 2016 by Patrice Lee Onwuka
Should Salaries Be Transparent? • PBS Point Taken May 3 2016 by Patrice Lee Onwuka
Staying Too Long? Life Expectancy; Girls & Sex • To The Contrary April 23 2016 by Patrice Lee Onwuka
Equal Pay Day & Women in the Workplace • PBS To The Contrary April 16 2016 by Patrice Lee Onwuka
The Liberty Vote & How Government Hurts Opportunity • Stossel March 12 2016 by Patrice Lee Onwuka
Goods Marketed To Women Cost More Than Identical Items For Men • After The Bell December 23 2015 by Patrice Lee Onwuka
Feds know best ... even with cosmetics December 4 2015 by Patrice Lee Onwuka
Social Security disability fund gets dealt another blow November 17 2015 by Patrice Lee Onwuka
Gravity CEO Defends $70,000 Minimum Salary, Says it was the Right Decision August 11 2015 by Patrice Lee Onwuka
Baltimore Mom Toya Graham, Carly Fiorina, Salma Hayek • To The Contrary May 2 2015 by Patrice Lee Onwuka
When did a 'blue-collar' job become a bad thing? May 1 2015 by Patrice Lee Onwuka
End of women's colleges?/Women's Mosque of America • To the Contrary March 28 2015 by Patrice Lee Onwuka
The [Un]Affordable Care Act/TurboTax data breach • WIBC Garrison February 19 2015 by Patrice Lee Onwuka
Women in STEM, Women CEOS, Hate Crimes on Rise? • To The Contrary February 14 2015 by Patrice Lee Onwuka
Generation Left Behind: Millennial's pummeling financial situation• WIBC Garrison December 18 2014 by Patrice Lee Onwuka
Women & Midterm Elections; Female Marines; Lean Together • PBS To The Contrary October 31 2014 by Patrice Lee Onwuka
Women CEOs; Egg Freezing; Male Survivors of Sexual Assault • PBS To The Contrary October 18 2014 by Patrice Lee Onwuka
Patronizing? WH uses Emojis to make its economic case to Gen Y • The Rick Amato Show October 13 2014 by Patrice Lee Onwuka
Zero Common Sense: America's feverish culture of alarmism • Stossel October 2 2014 by Patrice Lee Onwuka
NFL Abuse Scandals; Hillary Clinton & Economy • PBS To The Contrary September 19 2014 by Patrice Lee Onwuka
Border Crisis: Cleaning up unintended consequences from bad policy • PBS To The Contrary July 13 2014 by Patrice Lee Onwuka
Should there be achievement benchmarks before teachers get tenure? • The Rick Amato Show June 16 2014 by Patrice Lee Onwuka
For ObamaCare to be fiscally solvent 40% of enrollees must be under 35 • Rick Amato Show April 22 2014 by Patrice Lee Onwuka
Tax Freedom Day: Stop working for Uncle Sam and start working for ourselves • 1310 KFKA AM Colorado April 21 2014 by Patrice Lee Onwuka
How are young Americans reacting to ObamaCare? • CBN Newswatch March 27 2014 by Patrice Lee Onwuka
March Madness: A desperate and expensive attempt to sell ObamaCare • The Rick Amato Show March 18 2014 by Patrice Lee Onwuka
Reports show ObamaCare tax on medical devices resulting in the loss of about thousands of jobs • AM Colorado February 24 2014 by Patrice Lee Onwuka
Lax hiring practices of ObamaCare navigators • Conservative Commandos Radio Show February 13 2014 by Patrice Lee Onwuka
Lee • Convicted Felons Hired to Administer ObamaCare & Personal Info • Rick Amato Show (02.04.14) February 4 2014 by Patrice Lee Onwuka
Lee • What to expect from Obama's 5th State of the Union • Arise Xchange (01.28.14) January 28 2014 by Patrice Lee Onwuka
Lee • Who are the ObamaCare Orphans? ACA Olympics ad blitz costs what? • AM Colorado (01.13.14) January 13 2014 by Patrice Lee Onwuka
Debra Messing, leave black Trump supporters alone September 12 2019 by Patrice Lee Onwuka
Kamala Harris Misleads Black Women on Faux Equal Pay Holiday August 26 2019 by Patrice Lee Onwuka
On Black Women’s Equal Pay Day, we don’t have to be victims August 22 2019 by Patrice Lee Onwuka
Why didn't any Democratic candidates tell the truth about the gender pay gap? August 5 2019 by Patrice Lee Onwuka
A $15 Minimum Wage Would Put More Than A Million Out Of Work — And Tlaib Wants To Hit Even More July 24 2019 by Patrice Lee Onwuka
Let Women Entrepreneurs Be Their Own Bosses July 15 2019 by Patrice Lee Onwuka
Polling Shows Fewer People Are Proud to Be American, but We All Should Be July 4 2019 by Patrice Lee Onwuka
Forget Free College, Let’s Talk About Apprenticeships June 26 2019 by Patrice Lee Onwuka
Trump Delivers Second Chances for Black Inmates Re-entering Society June 14 2019 by Patrice Lee Onwuka
Kamala Harris Plan to 'Fix' the Wage Gap is Sure to Undermine Working Women May 28 2019 by Patrice Lee Onwuka
Millennials like me waited to start families. Paid leave will let me spend time with them. May 26 2019 by Patrice Lee Onwuka
This is a great time to be a working mother May 12 2019 by Patrice Lee Onwuka
Black Americans don't need reparations, we need jobs April 10 2019 by Patrice Lee Onwuka
New Parents Act an Innovative, Conservative Paid Parental Leave Plan March 29 2019 by Patrice Lee Onwuka
For Women's History Month, celebrate the conservative women that the media ignore March 26 2019 by Patrice Lee Onwuka
How parental leave aids families March 12 2019 by Patrice Lee Onwuka
Jussie Smollett Isn't Biggest Setback for Blacks, Ignoring Progress Is March 1 2019 by Patrice Lee Onwuka
The tax cuts didn't steal your tax refund February 28 2019 by Patrice Lee Onwuka
Women's March Has Inclusivity Problem and It's Not Just Anti-Semitism January 17 2019 by Patrice Lee Onwuka
Women need criminal justice reform November 26 2018 by Patrice Lee Onwuka
Post-Election Analysis: In Congress, It’s New Gridlock, Same Old Divisions November 13 2018 by Patrice Lee Onwuka
Blacks Reject Left's Regressive Agenda, Choose Trump's Confidence October 30 2018 by Patrice Lee Onwuka
Debt shouldn't hold back Stacey Abrams, but her victimhood mentality might October 29 2018 by Patrice Lee Onwuka
Elizabeth Warren is the problem with the diversity victimhood mentality October 17 2018 by Patrice Lee Onwuka
Don't underestimate Kanye (and Trump) – Rapper could successfully deliver for forgotten black communities October 11 2018 by Patrice Lee Onwuka
I Support Survivors and Stand With Kavanaugh October 5 2018 by Patrice Lee Onwuka
SNAP reforms in the farm bill can improve lives for Americans September 5 2018 by Patrice Lee Onwuka
Why Omarosa’s antics will fail to undermine Trump’s progress for black Americans August 20 2018 by Patrice Lee Onwuka
Playing Victim Card Won't Win at Empowering Black Women August 7 2018 by Patrice Lee Onwuka
Marco Rubio's paid leave plan would help black moms August 2 2018 by Patrice Lee Onwuka
Don't Match Maxine Waters' Incivility With Disrespect July 13 2018 by Patrice Lee Onwuka
Brett Kavanaugh's Supreme Court nomination offers a chance to fight sexism against all women July 12 2018 by Patrice Lee Onwuka
Why women on the Left are not marching for all separated kids July 3 2018 by Patrice Lee Onwuka
In the era of streaming shows, kids' TV regulations are stuck in the 1990s June 23 2018 by Patrice Lee Onwuka
Juneteenth Is Over but Progress for Blacks Must Grow June 21 2018 by Patrice Lee Onwuka
Starbucks' anti-bias training may serve up more harm than good June 2 2018 by Patrice Lee Onwuka
Anti-Bias Training Won't Help Starbucks May 29 2018 by Patrice Lee Onwuka
Michelle Obama's myopic view of women is what's wrong with feminism May 7 2018 by Patrice Lee Onwuka
Blacks Owe No Allegiance to the Left April 30 2018 by Patrice Lee Onwuka
Gender and race shouldn't define your politics April 30 2018 by Patrice Lee Onwuka
'Diamond & Silk' offer chance for bipartisan push back on social media censorship April 14 2018 by Patrice Lee Onwuka
A Real Free Market Might Save Cab Drivers From Financial Ruin April 4 2018 by Patrice Lee Onwuka
It's past time for the mainstream media to add opposing voices April 4 2018 by Patrice Lee Onwuka
Hillary Clinton’s sorry apology is why she’s no champion for women March 22 2018 by Patrice Lee Onwuka
Increased Competition Best Treatment For High Prescription Drugs Costs March 21 2018 by Patrice Lee Onwuka
‘Black Panther’ Exposes Immigrant Resentment in the Black Community March 15 2018 by Patrice Lee Onwuka
An immigrant's request: Keep these things in mind when debating immigration reform February 14 2018 by Patrice Lee Onwuka
When Did Joblessness Stop Mattering to Black Leaders? February 7 2018 by Patrice Lee Onwuka
The Grammys' #MeToo moment signals a dangerous direction for the movement January 30 2018 by Patrice Lee Onwuka
Black Americans' Record Employment, Tax Cuts and More January 9 2018 by Patrice Lee Onwuka
Hollywood's #TimesUp movement has been compromised by progressives January 9 2018 by Patrice Lee Onwuka
When States Hike the Minimum Wage, Women Lose Jobs December 22 2017 by Patrice Lee Onwuka
Women Can Get Excited About Tax Reform. Here’s Why! December 21 2017 by Patrice Lee Onwuka
Black Lives Matter Boycott Will Hurt Those It Claims to Help December 11 2017 by Patrice Lee Onwuka
Don't shed any tears for John Conyers December 5 2017 by Patrice Lee Onwuka
Richard Cordray's departure should end the campaign against payday loans November 20 2017 by Patrice Lee Onwuka
I Am Thankful for How Tax Reform Makes the American Dream Possible November 19 2017 by Patrice Lee Onwuka
Democratic women in the Senate were all for these tax reform principles until Trump proposed them October 30 2017 by Patrice Lee Onwuka
Trump Tax Cuts Will Help Black-Owned Businesses Thrive October 27 2017 by Patrice Lee Onwuka
Give Christopher Columbus a break October 9 2017 by Patrice Lee Onwuka
Black Women Leaving the Democratic Party, Cracking the Base September 27 2017 by Patrice Lee Onwuka
Betsy DeVos Stands for the Rights of Victims September 13 2017 by Patrice Lee Onwuka
NFL protests need to take a knee September 8 2017 by Patrice Lee Onwuka
Economic Agenda Will Do More for Black People Than Statue Removal August 28 2017 by Patrice Lee Onwuka
Government Can Hate A Name, But Still Must Respect It August 14 2017 by Patrice Lee Onwuka
The Google Diversity Memo Should Start the Conversation — Not End It August 8 2017 by Patrice Lee Onwuka
Entrepreneurship Is the Real Black Girl Magic August 7 2017 by Patrice Lee Onwuka
Serena Williams Swings But Misses With Black Women’s Equal Pay Day August 4 2017 by Patrice Lee Onwuka
New York's crackdown on dog-walking licenses is only hurting low-income workers July 21 2017 by Patrice Lee Onwuka
Business should back Larry Hogan's veto of paid sick leave July 18 2017 by Patrice Lee Onwuka
Dispelling the White House pay gap myth July 10 2017 by Patrice Lee Onwuka
Maybe it's time for the White House Office of Girls and Women to go July 4 2017 by Patrice Lee Onwuka
Why UK millennials voting for socialism could happen here, too June 27 2017 by Patrice Lee Onwuka
Dear Internet: Don’t Carry The ‘F**k You 2016’ Movement Into 2017 [VIDEO] December 31 2016 by Patrice Lee Onwuka
How To Win The 'War On Christmas' On Campus December 26 2016 by Patrice Lee Onwuka
The Scariest Part Of Halloween Is The Cultural Appropriation Police October 13 2016 by Patrice Lee Onwuka
Don't Major In DEBT September 12 2016 by Patrice Lee Onwuka
It's Time For Social Security Reform July 26 2016 by Patrice Lee Onwuka
Congratulations Class of 2016, You Majored in Debt May 13 2016 by Patrice Lee Onwuka
Should Over-the-Top College Acceptance Letters Woo Students? March 29 2016 by Patrice Lee Onwuka
Why Are So Many Working Americans Still Dependent on Food Stamps? March 17 2016 by Patrice Lee Onwuka
Nursing Needs More Competition March 14 2016 by Patrice Lee Onwuka
Reese Witherspoon’s Oscar-Worthy Truth For Young Women February 27 2016 by Patrice Lee Onwuka
Takeaways: Overtime Pay June 4 2019 by Patrice Lee Onwuka
Policy Focus: Overtime Pay May 30 2019 by Patrice Lee Onwuka
Takeaways: Welfare Reform 2.0 September 7 2018 by Patrice Lee Onwuka
Policy Focus: Welfare Reform 2.0 August 13 2018 by Patrice Lee Onwuka
Takeaways: What Drives the Wage Gap? April 5 2018 by Patrice Lee Onwuka
Takeaways: Why Requiring Work & Community Engagement is Good for Medicaid and the Poor January 29 2018 by Patrice Lee Onwuka
Takeaways: How Tax Reform Will Help Americans December 18 2017 by Patrice Lee Onwuka
Fact Sheet: Tax Reform is a Women's Issue September 15 2017 by Patrice Lee Onwuka
Policy Focus: Your Ideas, Your Rights - Intellectual Property in the 21st Century June 25 2017 by Patrice Lee Onwuka